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Literature summary for 4.1.2.10 extracted from

  • Lin, G.; Han, S.; Li, Z.
    Enzymic synthesis of (R)-cyanohydrins by three (R)-oxynitrilase sources in micro-aqueous organic medium (1999), Tetrahedron, 55, 3531-3540.
No PubMed abstract available

Application

Application Comment Organism
synthesis optically active cyanohydrins are expedient starting materials for preparation of alpha-hydroxyketones, alpha-hydroxy acids, beta-aminoalcohols, aminonitriles and aziridines Prunus armeniaca
synthesis optically active cyanoydrins are expedient starting materials for preparation of alpha-hydroxyketones, alpha-hydroxy acids, beta-aminoalcohols, aminonitriles and aziridines Rhaphiolepis bibas

Organism

Organism UniProt Comment Textmining
Prunus armeniaca
-
-
-
Prunus persica
-
-
-
Rhaphiolepis bibas
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
cyanide + 1-phenylethanone
-
Prunus armeniaca (2R)-2-hydroxy-2-phenylpropanenitrile
-
r
cyanide + 1-phenylethanone
-
Prunus persica (2R)-2-hydroxy-2-phenylpropanenitrile
-
?
cyanide + 4-methoxybenzaldehyde
-
Prunus armeniaca (2R)-hydroxy(4-methoxyphenyl)ethanenitrile
-
r
cyanide + 4-methoxybenzaldehyde
-
Prunus persica (2R)-hydroxy(4-methoxyphenyl)ethanenitrile
-
?
cyanide + 4-methoxybenzaldehyde
-
Rhaphiolepis bibas (2R)-hydroxy(4-methoxyphenyl)ethanenitrile
-
?
cyanide + benzaldehyde
-
Prunus armeniaca (R)-mandelonitrile more than 99% enantiomeric excess r
cyanide + benzaldehyde
-
Prunus persica (R)-mandelonitrile more than 99% enantiomeric excess ?
cyanide + benzaldehyde
-
Rhaphiolepis bibas (R)-mandelonitrile more than 99% enantiomeric excess ?
cyanide + furan-2-carbaldehyde
-
Prunus armeniaca (2R)-furan-2-yl(hydroxy)ethanenitrile
-
r
cyanide + furan-2-carbaldehyde
-
Prunus persica (2R)-furan-2-yl(hydroxy)ethanenitrile
-
?
cyanide + furan-2-carbaldehyde
-
Rhaphiolepis bibas (2R)-furan-2-yl(hydroxy)ethanenitrile
-
?
cyanide + hexan-2-one
-
Prunus armeniaca (2R)-2-hydroxy-2-methylhexanenitrile
-
r
cyanide + hexan-2-one
-
Prunus persica (2R)-2-hydroxy-2-methylhexanenitrile
-
?
cyanide + hexan-2-one
-
Rhaphiolepis bibas (2R)-2-hydroxy-2-methylhexanenitrile
-
?

Synonyms

Synonyms Comment Organism
(R)-Oxynitrilase
-
Prunus armeniaca
(R)-Oxynitrilase
-
Prunus persica
(R)-Oxynitrilase
-
Rhaphiolepis bibas
hydroynitrile lyase
-
Prunus armeniaca
hydroynitrile lyase
-
Prunus persica
hydroynitrile lyase
-
Rhaphiolepis bibas