Literature summary for 3.3.2.10 extracted from

Hwang, S.; Choi, C.Y.; Lee, E.Y.
Enantioconvergent bioconversion of p-chlorostyrene oxide to (R)-p-chlorophenyl-1,2-ethandiol by the bacterial epoxide hydrolase of Caulobacter crescentus (2008), Biotechnol. Lett., 30, 1219-1225.

Search for more literature for 3.3.2.10

Application

Application	Comment	Organism
synthesis	enantioselective hydrolysis of racemic styrene derivative via attack of the benzylic position results in formation of the correspponding (R)-diol with enantiomeric excess of up to 96% and more than 90% conversion	Caulobacter vibrioides

Cloned(Commentary)

Cloned (Comment)	Organism
expression in Escherichia coli	Caulobacter vibrioides

Organism

Organism	UniProt	Comment	Textmining
Caulobacter vibrioides	-	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
4-chlorostyrene oxide + H2O	-	Caulobacter vibrioides	(1R)-1-(4-chlorophenyl)ethane-1,2-diol	conversion of racemic substrate via attack of the benzylic position to R-diol with 96% enantiomeric excess	?
4-nitrostyrene oxide + H2O	-	Caulobacter vibrioides	(1R)-1-(4-nitrophenyl)ethane-1,2-diol	conversion of racemic substrate via attack of the benzylic position to R-diol with 80% enantiomeric excess	?
styrene oxide + H2O	-	Caulobacter vibrioides	(1R)-1-phenylethane-1,2-diol	conversion of racemic substrate via attack of the benzylic position to R-diol with 90% enantiomeric excess	?

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Release 2023.1 (January 2023)