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Literature summary for 3.1.1.78 extracted from

  • Pfitzner, A.; Stoeckigt, J.
    Polyneuridine aldehyde esterase: an unusually specific enzyme involved in the biosynthesis of sarpagine-type alkaloids (1983), J. Chem. Soc. Chem. Commun., 1983, 459-460.
No PubMed abstract available

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
polyneuridine aldehyde + H2O Rauvolfia serpentina Benth. ex Kurz key enzyme in the biosynthesis of sarpagine/ajmaline type alkaloids 16-epivellosimine + CO2 + methanol
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Organism

Organism UniProt Comment Textmining
Rauvolfia serpentina Benth. ex Kurz
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
polyneuridine aldehyde + H2O
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Rauvolfia serpentina Benth. ex Kurz 16-epivellosimine + CO2 + methanol 16-epivellosimine reacts to vellosimine ?
polyneuridine aldehyde + H2O key enzyme in the biosynthesis of sarpagine/ajmaline type alkaloids Rauvolfia serpentina Benth. ex Kurz 16-epivellosimine + CO2 + methanol
-
?