Organism | UniProt | Comment | Textmining |
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synthetic construct | - |
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Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
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additional information | in homogeneous aqueous solution containing titanium(III) citrate or titanium(III)-nitrilotriacetic acid as bulk electron donor, cobalamin, cobinamide, and cobamide are effective electron transfer mediators for the reduction of tetrachloroethene, trichloroethene, and trichlorofluoroethene. For a given chlorinated ethene, the reaction rate varies only slightly with pH and type of corrinoid present and is about 5 and 50 times faster for tetrachloroethene as compared to trichlorofluoroethene and trichloroethene, respectively. The first and rate-limiting step of the reduction of tetrachloroethene, trichloroethene, and trichlorofluoroethene by super-reduced corrinoids is a dissociative one-electron transfer yielding the corresponding vinyl radicals | synthetic construct | ? | - |
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