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Literature summary for 1.14.18.1 extracted from

  • Chaplin, M.F.
    Preparation and properties of an o-diphenol:O2 oxidoreductase from cocoa husk (1978), Phytochemistry, 17, 1897-1899.
No PubMed abstract available

Inhibitors

Inhibitors Comment Organism Structure
L-cysteine
-
Theobroma cacao
additional information product inhibition of o-quinones Theobroma cacao
quinol
-
Theobroma cacao

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
1.7
-
pyrogallol
-
Theobroma cacao
1.7
-
epicatechin
-
Theobroma cacao
2.1
-
catechin
-
Theobroma cacao
2.5
-
4-methylcatechol
-
Theobroma cacao
2.5
-
L-alpha-methyldopa
-
Theobroma cacao
13.7
-
L-adrenaline
-
Theobroma cacao
20
-
3-methylcatechol
-
Theobroma cacao
79
-
quinol
-
Theobroma cacao

Organism

Organism UniProt Comment Textmining
Theobroma cacao
-
cacao
-

Purification (Commentary)

Purification (Comment) Organism
-
Theobroma cacao

Source Tissue

Source Tissue Comment Organism Textmining
husk
-
Theobroma cacao
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
3-methylcatechol + O2
-
Theobroma cacao 3-methyl-o-benzoquinone + H2O
-
?
4-methylcatechol + O2
-
Theobroma cacao 4-methyl-1,2-benzoquinone + H2O
-
r
catechin + O2
-
Theobroma cacao catechin-O-quinone + H2O
-
r
catechol + 1/2 O2
-
Theobroma cacao 1,2-benzoquinone + H2O
-
?
D-catechin + O2
-
Theobroma cacao ?
-
?
epicatechin + O2
-
Theobroma cacao ?
-
?
L-adrenaline + O2
-
Theobroma cacao ?
-
?
L-alpha-methyldopa + O2
-
Theobroma cacao L-alpha-methyldopaquinone + H2O
-
r
L-epicatechin + O2
-
Theobroma cacao ?
-
?
pyrogallol + O2
-
Theobroma cacao ?
-
?
quinol + O2
-
Theobroma cacao quinone + H2O
-
?

Ki Value [mM]

Ki Value [mM] Ki Value maximum [mM] Inhibitor Comment Organism Structure
0.016
-
quinol
-
Theobroma cacao
0.025
-
L-cysteine
-
Theobroma cacao