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Literature summary for 1.14.13.22 extracted from

  • Branchaud, B.P.; Walsh, C.T.
    Functional group diversity in enzymatic oxygenation reactions catalyzed by bacterial flavin-containing cyclohexanone oxygenase (1985), J. Am. Chem. Soc., 107, 2153-2161.
No PubMed abstract available
Search for more literature for 1.14.13.22

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
0.0025
-
 n-Octylboronic acid
-
 Acinetobacter sp.
0.006
-
 cyclohexanone
-
 Acinetobacter sp.
0.009
-
 n-Butylboronic acid
-
 Acinetobacter sp.
0.024
-
 Thiane
-
 Acinetobacter sp.
0.025
-
 Butanal
-
 Acinetobacter sp.
0.03
-
 Phenyl allyl selenide
-
 Acinetobacter sp.
0.043
-
 phenylboronic acid
-
 Acinetobacter sp.
0.044
-
 Phenyl methyl selenide
-
 Acinetobacter sp.
0.11
-
 Phenyl allyl sulfide
-
 Acinetobacter sp.
0.178
-
 Thiane sulfoxide
-
 Acinetobacter sp.
0.22
-
 ethyl p-tolyl sulfide
-
 Acinetobacter sp.
0.33
-
 1-Phenyl-2-propanone
-
 Acinetobacter sp.
0.35
-
 2-Phenyl-1-ethanal
-
 Acinetobacter sp.
0.36
-
 triethyl phosphite
-
 Acinetobacter sp.
2.5
-
 Iodide
-
 Acinetobacter sp.

Organism

Organism UniProt Comment Textmining
Acinetobacter sp.
-
 NCIB 9871
-

Reaction

Reaction Comment Organism Reaction ID
cyclohexanone + NADPH + H+ + O2 = hexano-6-lactone + NADP+ + H2O general mechanistic scheme Acinetobacter sp.
a

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
1-phenyl-2-propanone + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
2-phenyl-1-ethanal + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
butanal + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
cyclohexanone + NADPH + O2
-
 Acinetobacter sp. 6-hexanolide + NADP+ + H2O
-
 ?
ethyl p-tolyl sulfide + NADPH + O2
-
 Acinetobacter sp. (S)-ethyl p-tolyl sulfoxide + NADP+ + H2O
-
 ?
iodide + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
n-butylboronic acid + NADPH + O2
-
 Acinetobacter sp. n-butanol + BO3- + NADP+ + H2O
-
 ?
n-octylboronic acid + NADPH + O2
-
 Acinetobacter sp. n-octanol + BO3- + NADP+ + H2O
-
 ?
phenyl allyl selenide + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
phenyl allyl sulfide + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
phenyl methyl selenide + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
phenylboronic acid + NADPH + O2
-
 Acinetobacter sp. phenol + BO3- + NADP+ + H2O
-
 ?
thiane + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
thiane sulfoxide + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?
triethylphosphite + NADPH + O2
-
 Acinetobacter sp. ?
-
 ?

Cofactor

Cofactor Comment Organism Structure
FAD
-
 Acinetobacter sp.
NADPH
-
 Acinetobacter sp.