Literature summary for 1.12.99.6 extracted from

Chiang, M.H.; Liu, Y.C.; Yang, S.T.; Lee, G.H.
Biomimetic model featuring the NH proton and bridging hydride related to a proposed intermediate in enzymatic H(2) production by Fe-only hydrogenase (2009), Inorg. Chem., 48, 7604-7612.

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Metals/Ions

Metals/Ions	Comment	Organism	Structure
Fe	iron azadithiolate phosphine-substituted complex and its protonated species featuring the NH proton and/or bridging Fe hydride, [Fe2(micro-S(CH2)2NnPr(H)m(CH2)2S)(micro-H)n(CO)4(PMe3)2]2 (2m+2n)+, mimic the active site of Fe-only hydrogenase. The ability to accept protons for the aza nitrogen and the Fe sites is essential for the enzymatic H2 production at the mild potential	synthetic construct

Organism

Organism	UniProt	Comment	Textmining
synthetic construct	-	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
H2 + oxidized acceptor	-	synthetic construct	H+ + reduced acceptor	-	?

Synonyms

Synonyms	Comment	Organism
Fe-only hydrogenase	-	synthetic construct

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Release 2023.1 (January 2023)