Literature summary for 1.11.1.B2 extracted from

Dong, J.J.; Fernandez-Fueyo, E.; Li, J.; Guo, Z.; Renirie, R.; Wever, R.; Hollmann, F.
Halofunctionalization of alkenes by vanadium chloroperoxidase from Curvularia inaequalis (2017), Chem. Commun. (Camb.), 53, 6207-6210 .

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Application

Application	Comment	Organism
synthesis	enzyme converts both aromatic and aliphatic alkenes into the corresponding halohydrins. Variation of pH value and addtion of ethanol as solvent leads to variation of product mixtures	Curvularia inaequalis

Organism

Organism	UniProt	Comment	Textmining
Curvularia inaequalis	P49053	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
cyclohexene + KBr + H2O2	-	Curvularia inaequalis	2-bromocyclohexan-1-ol + 2 H2O	-	?
hept-1-ene + KBr + H2O2	-	Curvularia inaequalis	1-bromoheptan-2-ol + 2 H2O	-	?
styrene + KBr + H2O2	-	Curvularia inaequalis	2-bromo-1-phenylethan-1-ol + 2-phenyloxirane + 2 H2O	-	?
styrene + KCl + H2O2	-	Curvularia inaequalis	2-chloro-1-phenylethan-1-ol + 2 H2O	-	?
[(1E)-prop-1-en-1-yl]benzene + KBr + H2O2	-	Curvularia inaequalis	(1R,2R)-2-bromo-1-phenylpropan-1-ol + 2 H2O	-	?
[(1Z)-prop-1-en-1-yl]benzene + KBr + H2O2	-	Curvularia inaequalis	(1R,2S)-2-bromo-1-phenylpropan-1-ol + 2 H2O	-	?

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Release 2023.1 (January 2023)