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Ligand (6aS,11aS)-2-dimethylallyl-3,6a,9-trihydroxypterocarpan

Basic Ligand Information

Molecular Structure

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Roles as Enzyme Ligand

In Vivo Product in Enzyme-catalyzed Reactions (1 result)

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EC NUMBER

PROVEN IN VIVO REACTION

REACTION DIAGRAM

LITERATURE

ENZYME 3D STRUCTURE

2.5.1.36

2 dimethylallyl diphosphate + 2 (6aS,11aS)-3,6a,9-trihydroxypterocarpan = 2 diphosphate + (6aS,11aS)-2-dimethylallyl-3,6a,9-trihydroxypterocarpan + (6aS,11aS)-4-dimethylallyl-3,6a,9-trihydroxypterocarpan

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Product in Enzyme-catalyzed Reactions (4 results)

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EC NUMBER

REACTION

REACTION DIAGRAM

LITERATURE

ENZYME 3D STRUCTURE

1.14.14.135

glyceollin II + NADPH + H+ + H2O = 2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + NADP+ + O2

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2.5.1.36

2 dimethylallyl diphosphate + 2 (6aS,11aS)-3,6a,9-trihydroxypterocarpan = 2 diphosphate + (6aS,11aS)-2-dimethylallyl-3,6a,9-trihydroxypterocarpan + (6aS,11aS)-4-dimethylallyl-3,6a,9-trihydroxypterocarpan

489902, 489903, 489904,

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2.5.1.36

dimethylallyl diphosphate + (6aS,11aS)-3,6a,9-trihydroxypterocarpan = diphosphate + (6aS,11aS)-2-dimethylallyl-3,6a,9-trihydroxypterocarpan + (6aS,11aS)-4-dimethylallyl-3,6a,9-trihydroxypterocarpan

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2.5.1.36

dimethylallyl diphosphate + (-)-glycinol = diphosphate + 2-dimethylallylglycinol

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2.5.1.36

3 entries

Enzyme Kinetic Parameters

References & Links

Literature References (3)

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BRENDA REFERENCE ID

PUBMED ID

TITLE

YEAR

AUTHORS

JOURNAL

VOLUME

PAGES

489902

-

Further studies on induction of enzymes of phytoalexin synthesis in soybean and cultured soybean cells

1983

Leube, J.; Grisebach, H.

Z. Naturforsch. C

38

730-735

489903

-

Induction of phytoalexin synthesis in soybean. Structure and reactions of naturally occuring and enzymatically prepared prenylated pterocarpans from elicitor-treated cotyledons and cell cultures of soybean

1981

Zaehringer, U.; Schaller, E.; Grisebach, H.

Z. Naturforsch. C

36

234-241

489904

571814

Induction of phytoalexin synthesis in soybean. Dimethylallylpyrophosphate:trihydroxypterocarpan dimethylallyl transferase from elicitor-induced cotyledons

1979

Zaehringer, U.; Ebel, J.; Mulheirn, L.J.; Lyne, R.L.; Grisebach, H.

FEBS Lett.

101

90-92

Links to other databases for (6aS,11aS)-2-dimethylallyl-3,6a,9-trihydroxypterocarpan

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ChEBI

PubChem