Ligand dihydromacarpine
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Basic Ligand Information
Molecular Structure

C22H19NO6
dihydromacarpine
RTVFIUBAXAZKSU-UHFFFAOYSA-N
Roles as Enzyme Ligand
In Vivo Substrate in Enzyme-catalyzed Reactions (1 result)
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Dihydromacarpine + O2 = ?
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Substrate in Enzyme-catalyzed Reactions (2 results)
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Dihydromacarpine + O2 = ?
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Dihydromacarpine + O2 = Macarpine + H2O2
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Product in Enzyme-catalyzed Reactions (1 result)
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S-adenosyl-L-methionine + 12-hydroxydihydrochelirubine = S-adenosyl-L-homocysteine + dihydromacarpine
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Enzyme Kinetic Parameters
KM Value (2 results)
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0.006
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dihydrosanguinarine
References & Links
Literature References (3)
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Enzymic 12-hydroxylation and 12-O-methylation of dihydrochelirubine in dihydromacarpine formation by Thalictrum bulgaricum
1994
Kammerer, L.; De-Eknamkul, W.; Zenk, M.H.
Phytochemistry
36
1409-1416
Partial purification and characterization of dihydrobenzophenanthridine oxidase from Eschscholtzia californica cell suspension cultures
1988
Schumacher, H.M.; Zenk, M.H.
Plant Cell Rep.
7
43-46
Purification and characterization of dihydrobenzophenanthridine oxidase from elicited Sanguinaria canadensis cell cultures
1992
Arakawa, H.; Clark, W.G.; Psenak, M.; Coscia, C.J.
Arch. Biochem. Biophys.
299
1-7
Links to other databases for dihydromacarpine