Ligand (+)-alpha-pinene
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Basic Ligand Information
Molecular Structure
C10H16
(+)-alpha-pinene
GRWFGVWFFZKLTI-RKDXNWHRSA-N
Roles as Enzyme Ligand
Substrate in Enzyme-catalyzed Reactions (3 results)
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(+)-alpha-pinene + NADPH + H+ + O2 = verbenol + NADP+ + H2O
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(+)-alpha-pinene + putidaredoxin + O2 = (+)-cis-verbenol + (+)-myrtenol + (+)-verbenone + oxidized putidaredoxin + H2O
(+)-alpha-pinene + putidaredoxin + O2 = ? + oxidized putidaredoxin + H2O
Product in Enzyme-catalyzed Reactions (8 results)
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(3R)-linalyl diphosphate = (+)-alpha-pinene + diphosphate
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(3S)-linalyl diphosphate = (+)-alpha-pinene + diphosphate
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(3R)-linalyl diphosphate = (+)-alpha-pinene + diphosphate
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(3S)-linalyl diphosphate = (+)-alpha-pinene + diphosphate
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geranyl diphosphate = (+)-alpha-pinene + diphosphate
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neryl diphosphate = (+)-alpha-pinene + diphosphate
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geranyl diphosphate = (+)-alpha-pinene + diphosphate
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geranyl diphosphate = (1R,5R)-(+)-alpha-pinene + diphosphate
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Inhibitor in Enzyme-catalyzed Reactions (1 result)
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50% inhibition at 0.4 mM
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3D Structure of Enzyme-Ligand-Complex (PDB) (1 result)
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Enzyme Kinetic Parameters
Ki Value (1 result)
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References & Links
Literature References (4)
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Engineering substrate recognition in catalysis by cytochrome P450cam
2003
Bell, S.G.; Chen, X.; Xu, F.; Rao, Z.; Wong, L.L.
Biochem. Soc. Trans.
31
558-562
Molecular recognition in (+)-alpha-pinene oxidation by cytochrome P450cam
2003
Bell, S.G.; Chen, X.; Sowden, R.J.; Xu, F.; Williams, J.N.; Wong, L.L.; Rao, Z.
J. Am. Chem. Soc.
125
705-714
Inhibition of acetylcholinesterase activity by bicyclic monoterpenoids
2005
Miyazawa, M.; Yamafuji, C.
J. Agric. Food Chem.
53
1765-1768
Functional characterization of myrcene hydroxylases from two geographically distinct Ips pini populations
2013
Song, M.; Kim, A.C.; Gorzalski, A.J.; MacLean, M.; Young, S.; Ginzel, M.D.; Blomquist, G.J.; Tittiger, C.
Insect Biochem. Mol. Biol.
43
336-343
Links to other databases for (+)-alpha-pinene
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