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Ligand 1,2,3,5-Tetrahydroxybenzene Please wait a moment until all data is loaded. This message will disappear when all data is loaded.
Basic Ligand Information Molecular Structure
C6 H6 O4
1,2,3,5-Tetrahydroxybenzene
AGPKZVBTJJNPAG-WHFBIAKZSA-N
Roles as Enzyme Ligand
In Vivo Substrate in Enzyme-catalyzed Reactions (1 result)Please wait a moment until the data is sorted. This message will disappear when the data is sorted.
1,2,3,5-tetrahydroxybenzene + pyrogallol = ?
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Substrate in Enzyme-catalyzed Reactions (6 results)
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1,2,3,5-tetrahydroxybenzene + 1,2,3,5-tetrahydroxybenzene = phloroglucinol + pentahydroxybenzene
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1,2,3,5-tetrahydroxybenzene + 1,2,3-trihydroxybenzene = 1,3,5-trihydroxybenzene + 1,2,3,5-tetrahydroxybenzene
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1,2,3,5-tetrahydroxybenzene + hydroxyhydroquinone = phloroglucinol + 1,2,4,5-tetrahydroxybenzene
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1,2,3,5-tetrahydroxybenzene + pyrogallol = ?
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1,2,3,5-tetrahydroxybenzene + pyrogallol = phloroglucinol + 1,2,3,5-tetrahydroxybenzene
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1,2,3,5-tetrahydroxybenzene + resorcinol = phloroglucinol + hydroxyhydroquinone
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Product in Enzyme-catalyzed Reactions (4 results)
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1,2,3,5-tetrahydroxybenzene + 1,2,3-trihydroxybenzene = 1,3,5-trihydroxybenzene + 1,2,3,5-tetrahydroxybenzene
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1,2,3,5-tetrahydroxybenzene + pyrogallol = phloroglucinol + 1,2,3,5-tetrahydroxybenzene
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1,2,4,5-tetrahydroxybenzene + pyrogallol = hydroxyhydroquinone + 1,2,3,5-tetrahydroxybenzene
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hydroxyhydroquinone + pyrogallol = resorcinol + 1,2,3,5-tetrahydroxybenzene
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Enzyme Kinetic Parameters
KM Value (1 result)
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References & Links Literature References (8)
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Phloroglucinol pathway in the strictly anaerobic Pelobacter acidigallici: fermentation of trihydroxybenzenes to acetate via triacetic acid
1992
Brune, A.; Schink, B.
Arch. Microbiol.
157
417-424
Pyrogallol-to-phloroglucinol conversion and other hydroxyl-transfer reactions catalyzed by cell extracts of Pelobacter acidigallici
1990
Brune, A.; Schink, B.
J. Bacteriol.
172
1070-1076
Sequential transhydroxylations converting hydroxyhydroquinone to phloroglucinol in the strictly anaerobic, fermentative bacterium Pelobacter massiliensis
1992
Brune, A.; Schnell, S.; Schink, B.
Appl. Environ. Microbiol.
58
1861-1868
Cloning, sequencing and heterologous expression of pyrogallol-phloroglucinol transhydroxylase from Pelobacter acidigallici
1999
Baas, D.; Retey, J.
Eur. J. Biochem.
265
896-901
One molecule of molybdopterin guanine dinucleotide is associated with each subunit of the heterodimeric Mo-Fe-S protein transhydroxylase of Pelobacter acidigallici as determined by SDS/PAGE and mass spectrometry
1996
Reichenbecher, W.; Ruediger, A.; Kroneck, P.M.H.; Schink, B.
Eur. J. Biochem.
237
406-413
Towards the reaction mechanism of pyrogallol-phloroglucinol transhydroxylase of Pelobacter acidigallici
1999
Reichenbecher, W.; Schink, B.
Biochim. Biophys. Acta
1430
245-253
Crystallization and preliminary x-ray analysis of the molybdenum-dependent pyrogallol-phloroglucinol transhydroxylase of Pelobacter acidigallici
2002
Abt, D.J.; Einsle, O.; Niessen, H.; Krieger, R.; Messerschmidt, A.; Schink, B.; Kroneck, P.M.H.
Acta Crystallogr. Sect. D
58
343-345
Investigation of the mechanism of action of pyrogallol-phloroglucinol transhydroxylase by using putative intermediates
2007
Paizs, C.; Bartlewski-Hof, U.; Retey, J.
Chemistry
13
2805-2811
Links to other databases for 1,2,3,5-Tetrahydroxybenzene
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