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Ligand benzyl acetate

Basic Ligand Information

Molecular Structure

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Roles as Enzyme Ligand

In Vivo Product in Enzyme-catalyzed Reactions (2 results)

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Show Natural Product (2 entries)

EC NUMBER

PROVEN IN VIVO REACTION

REACTION DIAGRAM

LITERATURE

ENZYME 3D STRUCTURE

1.14.13.92

phenylacetone + NADPH + H+ + O2 = benzyl acetate + NADP+ + H2O

0

-

2.3.1.224

acetyl-CoA + benzyl alcohol = CoA + benzyl acetate

0

-

Substrate in Enzyme-catalyzed Reactions (3 results)

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Show Substrate (3 entries)

EC NUMBER

REACTION

REACTION DIAGRAM

LITERATURE

ENZYME 3D STRUCTURE

3.1.1.1

benzyl acetate + H2O = benzyl alcohol + acetate

729255, 171026

-

3.1.1.2

benzyl acetate + H2O = benzyl alcohol + acetate

664111

-

3.1.8.1

benzyl acetate + H2O = ?

664111

-

Product in Enzyme-catalyzed Reactions (11 results)

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Show Product (11 entries)

EC NUMBER

REACTION

REACTION DIAGRAM

LITERATURE

ENZYME 3D STRUCTURE

1.14.13.54

phenylacetone + NADPH + H+ + O2 = benzylacetate + NADP+ + H2O

0

-

1.14.13.84

phenylacetone + NADPH + H+ + O2 = benzyl acetate + NADP+ + H2O

0

-

1.14.13.92

phenylacetone + NADPH + H+ + O2 = benzyl acetate + NADP+ + H2O

0

-

1.14.13.92

phenylacetone + NADPH + O2 = benzyl acetate + NADP+ + H2O

0

-

1.14.13.92

rac-2-ethylcyclohexanone + NADPH + O2 = benzyl acetate + NADP+ + H2O

0

-

1.14.13.92

3 entries

2.3.1.196

acetyl-CoA + benzyl alcohol = benzyl acetate + CoA

0

-

2.3.1.224

acetyl-CoA + benzyl alcohol = CoA + benzyl acetate

0

-

2.3.1.28

acetyl-CoA + benzyl alcohol = CoA + benzyl acetate

0

-

2.3.1.84

acetyl-CoA + benzyl alcohol = CoA + benzyl acetate

0

-

2.3.1.84

benzyl alcohol + acetyl-CoA = benzyl acetate + CoA

487567, 0

-

2.3.1.84

2 entries

2.5.1.47

O-acetyl-L-Ser + benzenethiol = L-cys + benzylacetate

0

-

Inhibitor in Enzyme-catalyzed Reactions (2 results)

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Show Inhibitors (2 entries)

EC NUMBER

COMMENTARY

LITERATURE

ENZYME 3D STRUCTURE

1.14.13.92

product inhibition

685231

-

1.14.14.92

0.5 mM, 21% inhibition

440254

-

3D Structure of Enzyme-Ligand-Complex (PDB) (6 results)

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Show 3D Structure of Enzyme-Ligand-Complex (PDB) (6 entries)

EC NUMBER

ENZYME 3D STRUCTURE

3.2.1.17

3huk, 3D-view

3.2.1.17

7l3j, 3D-view

3.2.1.17

7l3k, 3D-view

3.2.1.17

3huk, 3D-view

3.2.1.17

7l3j, 3D-view

3.2.1.17

7l3k, 3D-view

3.2.1.17

6 entries

Enzyme Kinetic Parameters

k_cat Value (Turnover Number) (4 results)

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Show Turnover Number (4 entries)

EC NUMBER

TURNOVER NUMBER [1/S]

TURNOVER NUMBER MAXIMUM [1/S]

COMMENTARY

LITERATURE

3.1.1.1

2.5

-

in 2.5 mM Bicine buffer, pH 8.3, at 30°C

729255

3.1.1.2

0.0008

-

-

664111

3.1.1.2

0.02

-

pH 8.0

664111

3.1.1.2

2 entries

3.1.8.1

0.02

-

about, pH 8.0, genetic variant PON1 G2E6

664111

K_M Value (2 results)

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Show KM Value (2 entries)

EC NUMBER

KM VALUE [MM]

KM VALUE MAXIMUM [MM]

COMMENTARY

LITERATURE

3.1.1.1

1.6

-

in 2.5 mM Bicine buffer, pH 8.3, at 30°C

729255

3.1.1.2

5

-

-

664111

References & Links

Literature References (6)

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Show Reference (6 entries)

BRENDA REFERENCE ID

PUBMED ID

TITLE

YEAR

AUTHORS

JOURNAL

VOLUME

PAGES

171026

7764506

Cloning of Pseudomonas fluorescens carboxylesterase gene and characterization of its product expressed in Escherichia coli

1994

Kim, Y.S.; Lee, H.B.; Choi, K.D.; Park, S.; Yoo, O.J.

Biosci. Biotechnol. Biochem.

58

111-116

440254

4040365

Properties of a membrane-associated benzoate-4-hydroxylase from Rhodotorula graminis

1985

McNamee, C.; Durham, D.R.

Biochem. Biophys. Res. Commun.

129

485-492

487567

11262031

Acetyl-CoA: Alcohol acetyltransferase activity and aroma formation in ripening melon fruits

2001

Shalit, M.; Katzir, N.; Tadmor, Y.; Larkov, O.; Burger, Y.; Shalekhet, F.; Lastochkin, E.; Ravid, U.; Amar, O.; Edelstein, M.; Karchi, Z.; Lewinsohn, E.

J. Agric. Food Chem.

49

794-799

664111

15835926

Structure-reactivity studies of serum paraoxonase PON1 suggest that its native activity is lactonase

2005

Khersonsky, O.; Tawfik, D.S.

Biochemistry

44

6371-6382

685231

18321069

Kinetic mechanism of phenylacetone monooxygenase from Thermobifida fusca

2008

Torres Pazmino, D.E.; Baas, B.J.; Janssen, D.B.; Fraaije, M.W.

Biochemistry

47

4082-4093

729255

24832101

Structural characterization and function determination of a nonspecific carboxylate esterase from the amidohydrolase superfamily with a promiscuous ability to hydrolyze methylphosphonate esters

2014

Xiang, D.F.; Kumaran, D.; Swaminathan, S.; Raushel, F.M.

Biochemistry

53

3476-3485

Links to other databases for benzyl acetate

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Show Links (1 entry)

ChEBI

PubChem