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Ligand bacteriochlorophyll a

Basic Ligand Information

Molecular Structure

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Roles as Enzyme Ligand

In Vivo Substrate in Enzyme-catalyzed Reactions (2 results)

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Show Natural Substrate (2 entries)

EC NUMBER

PROVEN IN VIVO REACTION

REACTION DIAGRAM

LITERATURE

ENZYME 3D STRUCTURE

1.3.1.111

bacteriochlorophyll a + 3 NADP+ = geranylgeranyl bacteriochlorophyllide a + 3 NADPH + 3 H+

736948, 692821, 692822, 736098, 735661

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3.1.1.14

bacteriochlorophyll a + H2O = phytol + bacteriochlorophyllide a

750145, 750116

-

In Vivo Product in Enzyme-catalyzed Reactions (1 result)

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Show Natural Product (1 entry)

EC NUMBER

PROVEN IN VIVO REACTION

REACTION DIAGRAM

LITERATURE

ENZYME 3D STRUCTURE

2.5.1.B43

bacteriochlorophyllide a + phytyl diphosphate = bacteriochlorophyll a + diphosphate

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Substrate in Enzyme-catalyzed Reactions (4 results)

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Show Substrate (4 entries)

EC NUMBER

REACTION

REACTION DIAGRAM

LITERATURE

ENZYME 3D STRUCTURE

1.3.1.111

bacteriochlorophyll a + 3 NADP+ = geranylgeranyl bacteriochlorophyllide a + 3 NADPH + 3 H+

736948, 692821, 692822, 736098, 735661

-

3.1.1.14

bacteriochlorophyll a + H2O = bacteriochlorophyllide a + phytol

80731

-

3.1.1.14

bacteriochlorophyll a + H2O = phytol + bacteriochlorophyllide a

750145, 750887, 750116

-

3.1.1.14

bacteriochlorophyll a + Triton X-100 + H2O = bacteriochlorophyllide a tritonyl ester

80739

-

3.1.1.14

3 entries

Product in Enzyme-catalyzed Reactions (1 result)

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Show Product (1 entry)

EC NUMBER

REACTION

REACTION DIAGRAM

LITERATURE

ENZYME 3D STRUCTURE

2.5.1.B43

bacteriochlorophyllide a + phytyl diphosphate = bacteriochlorophyll a + diphosphate

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Enzyme Kinetic Parameters

k_cat Value (Turnover Number) (2 results)

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Show Turnover Number (2 entries)

EC NUMBER

TURNOVER NUMBER [1/S]

TURNOVER NUMBER MAXIMUM [1/S]

COMMENTARY

LITERATURE

3.1.1.14

212.2

-

recombinant enzyme, pH 7.0, 60°C

750887

3.1.1.14

726.33

-

recombinant enzyme, pH 7.0, 60°C

750116

3.1.1.14

2 entries

K_M Value (3 results)

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Show KM Value (3 entries)

EC NUMBER

KM VALUE [MM]

KM VALUE MAXIMUM [MM]

COMMENTARY

LITERATURE

3.1.1.14

0.004

-

pH 7.5, 30°C

80731

3.1.1.14

0.0495

-

recombinant enzyme, pH 7.0, 60°C

750116

3.1.1.14

0.4603

-

recombinant enzyme, pH 7.0, 60°C

750887

3.1.1.14

3 entries

References & Links

Literature References (10)

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Show Reference (10 entries)

BRENDA REFERENCE ID

PUBMED ID

TITLE

YEAR

AUTHORS

JOURNAL

VOLUME

PAGES

80731

6819291

Purification and properties of chlorophyllase from greened rye seedlings

1982

Tanaka, K.; Kakuno, T.; Yamashita, J.; Horio, T.

J. Biochem.

92

1763-1773

80739

-

Triton X-100 reacts with chlorophyll in the presence of chlorophyllase

1987

Michalski, T.J.; Bradshaw, C.; Hunt, J.E.; Norris, J.R.; Katz, J.J.

FEBS Lett.

226

72-76

692821

10572128

Physical mapping and functional assignment of the geranylgeranyl-bacteriochlorophyll reductase gene, bchP, of Rhodobacter sphaeroides

1999

Addlesee, H.A.; Hunter, C.N.

J. Bacteriol.

181

7248-7255

692822

11872709

Rhodospirillum rubrum possesses a variant of the bchP gene, encoding geranylgeranyl-bacteriopheophytin reductase

2002

Addlesee, H.A.; Hunter, C.N.

J. Bacteriol.

184

1578-1586

735661

7947681

Molecular genetic analysis of terminal steps in bacteriochlorophyll a biosynthesis: characterization of a Rhodobacter capsulatus strain that synthesizes geranylgeraniol-esterified bacteriochlorophyll a

1994

Bollivar, D.

Biochemistry

33

12763-12768

736098

8766814

Cloning, sequencing and functional assignment of the chlorophyll biosynthesis gene, chlP, of Synechocystis sp. PCC 6803

1996

Addlesee, H.A.; Gibson, L.C.; Jensen, P.E.; Hunter, C.N.

FEBS Lett.

389

126-130

736948

18846281

Accumulation of chlorophyllous pigments esterified with the geranylgeranyl group and photosynthetic competence in the CT2256-deleted mutant of the green sulfur bacterium Chlorobium tepidum

2008

Harada, J.; Miyago, S.; Mizoguchi, T.; Azai, C.; Inoue, K.; Tamiaki, H.; Oh-oka, H.

Photochem. Photobiol. Sci.

7

1179-1187

750116

25828734

A novel recombinant chlorophyllase from cyanobacterium Cyanothece sp. ATCC 51142 for the production of bacteriochlorophyllide a

2016

Chou, Y.L.; Lee, Y.L.; Yen, C.C.; Chen, L.F.; Lee, L.C.; Shaw, J.F.

Biotechnol. Appl. Biochem.

63

371-377

750145

-

In search of engineered prokaryotic chlorophyllases a bioinformatics approach

2018

Sharafi, E.; Farmani, J.; Parizi, A.; Dehestani, A.

Biotechnol. Bioprocess Eng.

23

507-524

750887

26478543

A novel recombinant chlorophyllase1 from Chlamydomonas reinhardtii for the production of chlorophyllide derivatives

2015

Chou, Y.L.; Ko, C.Y.; Yen, C.C.; Chen, L.F.; Shaw, J.F.

J. Agric. Food Chem.

63

9496-9503

Links to other databases for bacteriochlorophyll a

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Show Links (1 entry)

ChEBI

PubChem

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