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BRENDA support

Ligand epsilon-rhodomycinone

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Basic Ligand Information

Molecular Structure
Picture of epsilon-rhodomycinone (click for magnification)
Molecular Formula
BRENDA Name
InChIKey
C22H20O9
epsilon-rhodomycinone
PYFOXRACBORDCT-GOSXWKPOSA-N
Pathway Source
Pathways
BRENDA
daunorubicin biosynthesis
KEGG
Biosynthesis of secondary metabolites, Biosynthesis of type II polyketide products
MetaCyc
daunorubicin biosynthesis


Show all pahtways known for Show all BRENDA pathways known for epsilon-rhodomycinone

Roles as Enzyme Ligand

In Vivo Product in Enzyme-catalyzed Reactions (1 result)

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EC NUMBER
PROVEN IN VIVO REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
aklavinone + NADPH + H+ + O2 = epsilon-rhodomycinone + NADP+ + H2O
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Substrate in Enzyme-catalyzed Reactions (1 result)

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EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
dTDP-L-2-deoxyfucose + epsilon-rhodomycinone = dTDP + 4-O-(2-deoxy-alpha-L-fucosyl)-epsilon-rhodomycinone
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Product in Enzyme-catalyzed Reactions (3 results)

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EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
maggiemycin + NADPH + H+ = epsilon-rhodomycinone + NADP+
show the reaction diagram
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Enzyme Kinetic Parameters

kcat Value (Turnover Number) (1 result)

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EC NUMBER
TURNOVER NUMBER [1/S]
TURNOVER NUMBER MAXIMUM [1/S]
COMMENTARY
LITERATURE
0.001
-
with dTDP-L-2-deoxyfucose as cosubstrate, in 75 mM Tris (pH 7.5), 10 mM MgCl2, at 25°C

KM Value (1 result)

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EC NUMBER
KM VALUE [MM]
KM VALUE MAXIMUM [MM]
COMMENTARY
LITERATURE
0.046
-
with dTDP-L-2-deoxyfucose as cosubstrate, in 75 mM Tris (pH 7.5), 10 mM MgCl2, at 25°C

References & Links

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Links to other databases for epsilon-rhodomycinone

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ChEBI
PubChem
ChEBI
PubChem