Ligand ferrocyanide

Please wait a moment until all data is loaded. This message will disappear when all data is loaded.

Basic Ligand Information

Molecular Structure
Picture of ferrocyanide (click for magnification)
Molecular Formula
BRENDA Name
InChIKey
C6FeN6
ferrocyanide
ORXDSIPBTFAEKJ-UHFFFAOYSA-N
Synonyms:
Fe(CN)6 4-, Fe(CN)64-, hexacyanoferrate(II), reduced ferricyanide, [Fe(CN)6]4-

Roles as Enzyme Ligand

In Vivo Substrate in Enzyme-catalyzed Reactions (1 result)

EC NUMBER
PROVEN IN VIVO REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
ferrocyanide + O2 = ?
show the reaction diagram
-

In Vivo Product in Enzyme-catalyzed Reactions (3 results)

EC NUMBER
PROVEN IN VIVO REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
(S)-mandelate + 2 ferricyanide = benzoylformic acid + 2 ferrocyanide + 2 H+
show the reaction diagram
-
-
taurine + H2O + ferricyanide = 2-sulfoacetaldehyde + NH3 + ferrocyanide
show the reaction diagram
-
-
thiocyanate + 2 ferricyanide + H2O = cyanate + sulfur + 2 ferrocyanide + 2 H+
show the reaction diagram
-
-

Substrate in Enzyme-catalyzed Reactions (41 results)

EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
ferrocyanide + O2 = ?
show the reaction diagram
-
ferrocyanide + O2 = ?
show the reaction diagram
-
ferrocyanide + H2O2 = ferricyanide + H2O
show the reaction diagram
-
ferrocyanide + H+ + H2O2 = ferricyanide + H2O
show the reaction diagram
-
ferrocyanide + H2O2 = ferricyanide + OH-
show the reaction diagram
-
tyramine + ascorbate + ferrocyanide = octopamine + dehydroascorbate + ?
show the reaction diagram
-
hippuric acid + ferrocyanide + O2 = alpha-hydroxyhippuric acid + ? + H2O
show the reaction diagram
-
2 ferrocyanide + NADP+ + H+ = 2 ferricyanide + NADPH
show the reaction diagram
-
succinate + ferrocyanide = fumarate + ferricyanide
show the reaction diagram
-

Product in Enzyme-catalyzed Reactions (246 results)

EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
2 ferricyanide + NADPH = 2 ferrocyanide + NADP+ + H+
show the reaction diagram
-
-
L-lactate + ferricyanide = pyruvate + ferrocyanide + H+
show the reaction diagram
-
-
D-lactate + ferricyanide = pyruvate + ferrocyanide
show the reaction diagram
-
-
D-glucose + ferricyanide = 2-dehydro-D-glucose + ferrocyanide
show the reaction diagram
-
-
polyvinyl alcohol + ferricyanide = polyvinylketone + ferrocyanide
show the reaction diagram
-
-
D-galactopyranose + ferricyanide = D-galacto-hexodialdose + ferrocyanide
show the reaction diagram
-
D-lactate + ferricyanide = pyruvate + ferrocyanide
show the reaction diagram
-
-
D-glucose + ferricyanide = D-glucono-1,5-lactone + ferrocyanide
show the reaction diagram
-
-
sn-glycerol 3-phosphate + ferricyanide = glycerone phosphate + ferrocyanide
show the reaction diagram
-
-
(R)-Pantolactone + (Fe(CN)6)3- = 2-Dehydropantonolactone + Fe(CN)64-
show the reaction diagram
-
-
aldopyranose + ferricyanide = 2-aldoketose + ferrocyanide
show the reaction diagram
-
-
2-dehydro-D-gluconate + ferricyanide = 2,5-didehydro-D-gluconate + ferrocyanide
show the reaction diagram
-
-
(R)-lactate + ferricyanide = pyruvate + ferrocyanide
show the reaction diagram
-
-
H2O + ferricyanide + hv = O2 + ferrocyanide
show the reaction diagram
-
-
ferricyanide + H2O2 = ferrocyanide + H2O
show the reaction diagram
-
-
4-hydroxybenzoate + NADPH + ferricyanide = protocatechuate + NADP+ + ferrocyanide
show the reaction diagram
-
2 ferricyanide + NADPH = 2 ferrocyanide + NADP+ + H+
show the reaction diagram
-
-
formate + ferricyanide = CO2 + ferrocyanide + H+
show the reaction diagram
-
-
2 ferricyanide + NADH = 2 ferrocyanide + NAD+ + H+
show the reaction diagram
-
-
pyruvate + CoA + ferricyanide = acetyl-CoA + CO2 + ferrocyanide
show the reaction diagram
-
-
pyruvate + phosphate + ferricyanide + H2O = acetyl phosphate + ferrocyanide + H2O2
show the reaction diagram
-
benzaldehyde + 2 ferricyanide + H2O = benzoate + 2 ferrocyanide + 2 H+
show the reaction diagram
-
-
succinate + ferricyanide = fumarate + ferrocyanide
show the reaction diagram
-
-
succinate + ferricyanide = fumarate + ferrocyanide
show the reaction diagram
-
-
ferricyanide + NADPH + H+ = ferrocyanide + NADP+
show the reaction diagram
-
-
taurine + H2O + ferricyanide = 2-sulfoacetaldehyde + NH3 + ferrocyanide
show the reaction diagram
-
-
2 ferricyanide + NADH = 2 ferrocyanide + NAD+ + H+
show the reaction diagram
-
-
L-proline + ferricyanide + H2O = (S)-1-pyrroline-5-carboxylate + ferrocyanide
show the reaction diagram
-
-
N6-(2-isopentenyl)adenine 9-beta-D-riboside + ferricyanide + H2O = adenine 9-beta-D-riboside + 3-methylbut-2-enal + ferrocyanide
show the reaction diagram
-
-
L-proline + ferricyanide = DELTA1-pyrroline-5-carboxylate + ferrocyanide
show the reaction diagram
-
-
Fe(CN)6 3- + NADPH = Fe(CN)6 4- + NADP+
show the reaction diagram
-
-
2 ferricyanide + NADPH = 2 ferrocyanide + NADP+ + H+
show the reaction diagram
-
-
2 ferricyanide + NADH = 2 ferrocyanide + NAD+ + H+
show the reaction diagram
-
-
2 ferricyanide + NADH = 2 ferrocyanide + NAD+ + H+
show the reaction diagram
-
-
2 ferricyanide + NADPH = 2 ferrocyanide + NADP+ + H+
show the reaction diagram
-
-
2 ferricyanide + NADPH = 2 ferrocyanide + NADP+ + H+
show the reaction diagram
-
2 ferricyanide + NADH = 2 ferrocyanide + NAD+ + H+
show the reaction diagram
-
2 ferricyanide + NADH = 2 ferrocyanide + NAD+ + H+
show the reaction diagram
-
-
ferricyanide + NADPH + H+ = ferrocyanide + NADP+
show the reaction diagram
-
-
thiocyanate + 2 ferricyanide + H2O = cyanate + sulfur + 2 ferrocyanide + 2 H+
show the reaction diagram
-
-
sulfite + ferricyanide = sulfate + ferrocyanide
show the reaction diagram
-
-
2 thiosulfate + ferricyanide = tetrathionate + ferrocyanide
show the reaction diagram
-
-
ubiquinol + 2 ferricyanide = ubiquinone + 2 ferrocyanide + 2 H+
show the reaction diagram
-
-
2 ferricyanide + NADH + n Na+/in = 2 ferrocyanide + NAD+ + H+ + n Na+/out
show the reaction diagram
-
-

Activator in Enzyme-catalyzed Reactions (2 results)

EC NUMBER
COMMENTARY
LITERATURE
ENZYME 3D STRUCTURE
converts inactive myeloperoxidase compound II into active myeloperoxidase
-
about 112% activity at 5 mM
-

Inhibitor in Enzyme-catalyzed Reactions (7 results)

EC NUMBER
COMMENTARY
LITERATURE
ENZYME 3D STRUCTURE
0.7 mM, 50% inhibition of brominating activity
-
inhibiting above 0.6 mM
-
1 mM, complete loss of activity
-

Enzyme Kinetic Parameters

kcat Value (Turnover Number) (13 results)

EC NUMBER
TURNOVER NUMBER [1/S]
TURNOVER NUMBER MAXIMUM [1/S]
COMMENTARY
LITERATURE
0.43
-
at pH 8.7 and 22C

KM Value (15 results)

EC NUMBER
KM VALUE [MM]
KM VALUE MAXIMUM [MM]
COMMENTARY
LITERATURE
0.0074
-
at pH 8.7 and 22C
1.14
-
pH 6.5, 55C

Ki Value (1 result)

EC NUMBER
KI VALUE [MM]
KI VALUE MAXIMUM [MM]
COMMENTARY
LITERATURE
4.2
-
pH 7.5, 21C

References & Links

Links to other databases for ferrocyanide

ChEBI
PubChem
-
PubChem