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Ligand (1R,4S)-1-hydroxy-2-oxolimonene Please wait a moment until all data is loaded. This message will disappear when all data is loaded.
Basic Ligand Information Molecular Structure
C1 0 H1 6 O2
(1R,4S)-1-hydroxy-2-oxolimonene
JEQLRDRDFLXSHY-WCBMZHEXSA-N
(1R,4S)-1-hydroxymenth-8-en-2-one
Roles as Enzyme Ligand
Substrate in Enzyme-catalyzed Reactions (2 results)
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(1R,4S)-1-hydroxy-2-oxolimonene + NADPH + H+ + O2 = (3S)-3-isopropenyl-6-oxoheptanoate + NADP+ + H2O
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(1R,4S)-1-hydroxy-2-oxolimonene + NADPH + H+ + O2 = 3-isopropenyl-6-oxoheptanoate + NADP+ + H2O
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Product in Enzyme-catalyzed Reactions (1 result)
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(1R,2R,4S)-limonene-1,2-diol + NAD+ = (1R,4S)-1-hydroxy-2-oxolimonene + (1R,2S,4S)-limonene-1,2-diol + NADH + H+
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Enzyme Kinetic Parameters
kcat Value (Turnover Number) (1 result)
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4.9
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30°C and glyine/NaOH buffer, pH 9.5
References & Links Literature References (2)
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Rhodococcus erythropolis DCL14 contains a novel degradation pathway for limonene
1999
van der Werf, M.J.; Swarts, H.J.; de Bont, J.A.
Appl. Environ. Microbiol.
65
2092-2102
Purification and characterization of a Baeyer-Villiger mono-oxygenase from Rhodococcus erythropolis DCL14 involved in three different monocyclic monoterpene degradation pathways
2000
van der Werf, M.J.
Biochem. J.
347 Pt 3
693-701
Links to other databases for (1R,4S)-1-hydroxy-2-oxolimonene