Ligand copalyl diphosphate

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Basic Ligand Information

Molecular Structure
Picture of copalyl diphosphate (click for magnification)
Molecular Formula
BRENDA Name
InChIKey
C20H36O7P2
copalyl diphosphate
JCAIWDXKLCEQEO-ATPOGHATSA-N
Synonyms:
(+)-copalyl-diphosphate, (+)-copalyl diphosphate, (2E)-3-methyl-5-[(1S,4aS,8aS)-5,5,8a-trimethyl-2-methylidenedecahydronaphthalen-1-yl]pent-2-en-1-yl trihydrogen diphosphate, 9alpha-copalyl diphosphate


Show all pahtways known for Show all BRENDA pathways known for copalyl diphosphate

Roles as Enzyme Ligand

In Vivo Substrate in Enzyme-catalyzed Reactions (17 results)

EC NUMBER
PROVEN IN VIVO REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
(+)-copalyl diphosphate = miltiradiene + diphosphate
show the reaction diagram
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(+)-copalyl diphosphate = pimara-8(14),15-diene + diphosphate
show the reaction diagram
-
(+)-copalyl diphosphate + H2O = nezukol + diphosphate
show the reaction diagram
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copalyl diphosphate = sandaracopimaradiene + diphosphate
show the reaction diagram
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(+)-copalyl diphosphate = labda-8(13),13(16),14-triene + diphosphate
show the reaction diagram
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(+)-copalyl diphosphate = labda-8(17),12,14-triene + diphosphate
show the reaction diagram
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(+)-copalyl diphosphate = abieta-8(14),12-diene + diphosphate
show the reaction diagram
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9alpha-copalyl diphosphate = stemod-13(17)-ene + diphosphate
show the reaction diagram
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9alpha-copalyl diphosphate = 9beta-pimara-7,15-diene + diphosphate
show the reaction diagram
-
9alpha-copalyl diphosphate + H2O = aphidicolan-16beta-ol + diphosphate
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(+)-copalyl diphosphate = isopimara-7,15-diene + diphosphate
show the reaction diagram
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copalyl diphosphate = ent-kaurene + diphosphate
show the reaction diagram
-

In Vivo Product in Enzyme-catalyzed Reactions (5 results)

EC NUMBER
PROVEN IN VIVO REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
geranylgeranyl diphosphate = (+)-copalyl diphosphate
show the reaction diagram
-
-
geranylgeranyl diphosphate = copalyl diphosphate
show the reaction diagram
-
geranylgeranyl diphosphate = 9alpha-copalyl diphosphate
show the reaction diagram
-
-

Substrate in Enzyme-catalyzed Reactions (41 results)

EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
copalyl diphosphate + H2O = copalol + diphosphate
show the reaction diagram
-
copalyl diphosphate + H2O = (+)-copalol + manool + 13-epi-manool + diphosphate
show the reaction diagram
-
copalyl diphosphate + H2O = (+)-copalol + manool + 13-epi-manool + diphosphate
show the reaction diagram
-
(+)-copalyl diphosphate = miltiradiene + diphosphate
show the reaction diagram
-
(+)-copalyl diphosphate + H2O = nezukol + diphosphate
show the reaction diagram
-
copalyl diphosphate = sandaracopimaradiene + diphosphate
show the reaction diagram
-
(+)-copalyl diphosphate = labda-8(13),13(16),14-triene + diphosphate
show the reaction diagram
-
(+)-copalyl diphosphate = labda-8(17),12,14-triene + diphosphate
show the reaction diagram
-
9alpha-copalyl diphosphate = stemod-13(17)-ene + diphosphate
show the reaction diagram
-
9alpha-copalyl diphosphate + H2O = aphidicolan-16beta-ol + diphosphate
show the reaction diagram
-
(+)-copalyl diphosphate + H2O = phyllocladan-16alpha-ol + phosphate
show the reaction diagram
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(+)-copalyl diphosphate = sclarene + diphosphate
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(+)-copalyl diphosphate + H2O = (+)-copalol + diphosphate
show the reaction diagram
-
(+)-copalyl diphosphate + H2O = manool + diphosphate
show the reaction diagram
-
(+)-copalyl diphosphate + H2O = 13-epi-manool + diphosphate
show the reaction diagram
-

Product in Enzyme-catalyzed Reactions (6 results)

EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
geranylgeranyl diphosphate = (+)-copalyl diphosphate
show the reaction diagram
-
-
geranylgeranyl diphosphate + diphosphate = (+)-copalyl diphosphate
show the reaction diagram
-
-
geranylgeranyl diphosphate = copalyl diphosphate
show the reaction diagram
-
geranylgeranyl diphosphate = 9alpha-copalyl diphosphate
show the reaction diagram
-
-

Inhibitor in Enzyme-catalyzed Reactions (2 results)

EC NUMBER
COMMENTARY
LITERATURE
ENZYME 3D STRUCTURE

Enzyme Kinetic Parameters

kcat Value (Turnover Number) (10 results)

EC NUMBER
TURNOVER NUMBER [1/S]
TURNOVER NUMBER MAXIMUM [1/S]
COMMENTARY
LITERATURE
0.00117
-
at pH 8

KM Value (30 results)

EC NUMBER
KM VALUE [MM]
KM VALUE MAXIMUM [MM]
COMMENTARY
LITERATURE
0.00023
-
at pH 8

References & Links

Links to other databases for copalyl diphosphate

ChEBI
PubChem
ChEBI
PubChem