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Substrate-triggered formation and remarkable stability of the C-H bond-cleaving chloroferryl intermediate in the aliphatic halogenase, SyrB2
2009
Matthews, M.L.; Krest, C.M.; Barr, E.W.; Vaillancourt, F.H.; Walsh, C.T.; Green, M.T.; Krebs, C.; Bollinger, J.M.
Biochemistry
48
4331-4343
Dichlorination and bromination of a threonyl-S-carrier protein by the non-heme FeII halogenase SyrB2
2006
Vaillancourt, F.; Vosburg, D.; Walsh, C.
ChemBioChem
7
748-752
SyrB2 in syringomycin E biosynthesis is a nonheme FeII alpha-ketoglutarate- and O2-dependent halogenase
2005
Vaillancourt, F.H.; Yin, J.; Walsh, C.T.
Proc. Natl. Acad. Sci. USA
102
10111-10116
Substrate positioning controls the partition between halogenation and hydroxylation in the aliphatic halogenase, SyrB2
2009
Matthews, M.L.; Neumann, C.S.; Miles, L.A.; Grove, T.L.; Booker, S.J.; Krebs, C.; Walsh, C.T.; Bollinger, J.M.
Proc. Natl. Acad. Sci. USA
106
17723-17728