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Ligand 4-hydroxyphenyl acetate Please wait a moment until all data is loaded. This message will disappear when all data is loaded.
Basic Ligand Information Molecular Structure
C8 H8 O3
4-hydroxyphenyl acetate
HBMCQTHGYMTCOF-UHFFFAOYSA-N
acetic acid 4-hydroxyphenyl ester, p-hydroxyphenyl acetate
Roles as Enzyme Ligand
In Vivo Product in Enzyme-catalyzed Reactions (2 results)Please wait a moment until the data is sorted. This message will disappear when the data is sorted.
(4-hydroxyphenyl)ethan-1-one + NADPH + O2 = 4-hydroxyphenyl acetate + NADP+ + H2O
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4-hydroxyacetophenone + NADPH + H+ + O2 = 4-hydroxyphenyl acetate + NADP+ + H2O
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Substrate in Enzyme-catalyzed Reactions (1 result)
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4-hydroxyphenyl acetate + H2O = 4-hydroxyphenol + acetate
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Product in Enzyme-catalyzed Reactions (4 results)
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(4-hydroxyphenyl)ethan-1-one + NADPH + O2 = 4-hydroxyphenyl acetate + NADP+ + H2O
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4-hydroxyacetophenone + NADH + H+ + O2 = 4-hydroxyphenyl acetate + NAD+ + H2O
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4-hydroxyacetophenone + NADPH + H+ + O2 = 4-hydroxyphenyl acetate + NADP+ + H2O
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4-hydroxyacetophenone + NADPH + O2 = acetic acid 4-hydroxyphenyl ester + NADP+ + O2
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3D Structure of Enzyme-Ligand-Complex (PDB) (7 results)
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Enzyme Kinetic Parameters
References & Links Literature References (5)
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4- Hydroxyacetophenone monooxygenase from Pseudomonas fluorescens ACB: a novel flavoprotein catalyzing Baeyer-Villiger oxidation of aromatic compounds
2001
Kamerbeek, N.M.; Moonen, M.J.; van der Ven, J.G.; van Berkel, W.J.H.; Fraaije, M.W.; Janssen, D.B.
Eur. J. Biochem.
268
2547-2557
Substrate specificity and enantioselectivity of 4-hydroxyacetophenone monooxygenase
2003
Kamerbeek, N.M.; Olsthoorn, A.J.J.; Fraaije, M.W.; Janssen, D.B.
Appl. Environ. Microbiol.
69
419-426
Identifying determinants of NADPH specificity in Baeyer-Villiger monooxygenases
2004
Kamerbeek, N.M.; Fraaije, M.W.; Janssen, D.B.
Eur. J. Biochem.
271
2107-2116
Conversion of 4-hydroxyacetophenone into 4-phenyl acetate by a flavin adenine dinucleotide-containing Baeyer-Villiger-type monooxygenase
2000
Tanner, A.; Hopper, D.J.
J. Bacteriol.
182
6565-6569
Structural characterization and function determination of a nonspecific carboxylate esterase from the amidohydrolase superfamily with a promiscuous ability to hydrolyze methylphosphonate esters
2014
Xiang, D.F.; Kumaran, D.; Swaminathan, S.; Raushel, F.M.
Biochemistry
53
3476-3485
Links to other databases for 4-hydroxyphenyl acetate
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