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Ligand bacteriochlorophyllide Please wait a moment until all data is loaded. This message will disappear when all data is loaded.
Basic Ligand Information Molecular Structure
C3 5 H3 6 MgN4 O6
bacteriochlorophyllide
IRCCOQFJBKCMIV-CUSHWANBSA-L
2-acetyl-2-devinylchlorophyllide a, 3-acetyl-3-devinylchlorophyllide a
Roles as Enzyme Ligand
In Vivo Substrate in Enzyme-catalyzed Reactions (1 result)
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3-acetyl-3-devinylchlorophyllide a + 2 reduced ferredoxin [iron-sulfur] cluster + ATP + H2O + 2 H+ = bacteriochlorophyllide a + 2 oxidized ferredoxin [iron-sulfur] cluster + ADP + phosphate
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In Vivo Product in Enzyme-catalyzed Reactions (3 results)
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2-devinyl-2-(1-hydroxyethyl)chlorophyllide a + NAD+ = 2-acetyl-2-devinylchlorophyllide a + NADH + H+
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3-devinyl-3-(1-hydroxyethyl)chlorophyllide a + NAD+ = 3-acetyl-3-devinylchlorophyllide a + NADH + H+
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bacteriochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster + ADP + phosphate = 3-acetyl-3-devinylchlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + ATP + H2O + H+
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Substrate in Enzyme-catalyzed Reactions (1 result)
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3-acetyl-3-devinylchlorophyllide a + 2 reduced ferredoxin [iron-sulfur] cluster + ATP + H2O + 2 H+ = bacteriochlorophyllide a + 2 oxidized ferredoxin [iron-sulfur] cluster + ADP + phosphate
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Product in Enzyme-catalyzed Reactions (4 results)
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2-devinyl-2-(1-hydroxyethyl)chlorophyllide a + NAD+ = 2-acetyl-2-devinylchlorophyllide a + NADH + H+
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3-devinyl-3-(1-hydroxyethyl)chlorophyllide a + NAD+ = 3-acetyl-3-devinylchlorophyllide a + NADH + H+
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bacteriochlorophyllide a + oxidized ferredoxin [iron-sulfur] cluster + ADP + phosphate = 3-acetyl-3-devinylchlorophyllide a + reduced ferredoxin [iron-sulfur] cluster + ATP + H2O + H+
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bacteriochlorophyll + H2o = bacteriochlorophyllide + phytol
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Enzyme Kinetic Parameters
References & Links Literature References (3)
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Chlorophyllide a oxidoreductase preferentially catalyzes 8-vinyl reduction over B-ring reduction of 8-vinyl chlorophyllide a in the late steps of bacteriochlorophyll biosynthesis
2020
Yamamoto, H.; Mizoguchi, T.; Tsukatani, Y.; Tamiaki, H.; Kurisu, G.; Fujita, Y.
ChemBioChem
21
1760-1766
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Rapid C8-vinyl reduction of divinyl-chlorophyllide a by BciA from Rhodobacter capsulatus
2018
Azai, C.; Kobayashi, M.; Mizoguchi, T.; Tamiaki, H.; Terauchi, K.; Tsukatani, Y.
J. Photochem. Photobiol. A
353
661-666
Expression, purification, and activity analysis of chlorophyllide oxidoreductase and Ni2+-sirohydrochlorin a,c-diamide reductase
2019
Moser, J.; Jasper, J.; Ramos, J.; Sowa, S.; Layer, G.
Methods Mol. Biol.
1876
125-140
Links to other databases for bacteriochlorophyllide