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Enzyme Kinetic Parameters
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Ligand 4-chloro-beta-nitrostyrene

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Basic Ligand Information

Molecular Structure

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Molecular Formula

BRENDA Name

InChIKey

C₈H₆ClNO₂

4-chloro-beta-nitrostyrene

GLJATYFHELDGEA-AATRIKPKSA-N

Synonyms:

1-chloro-4-[(E)-2-nitroethenyl]benzene, trans-p-chloro-beta-nitrostyrene

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Roles as Enzyme Ligand

Substrate in Enzyme-catalyzed Reactions (3 results)

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EC NUMBER

REACTION

REACTION DIAGRAM

LITERATURE

ENZYME 3D STRUCTURE

5.3.2.6

acetaldehyde + 1-chloro-4-[(E)-2-nitroethenyl]benzene = 4-(4-chlorophenyl)-5-nitropentan-2-one

748742

5.3.2.6

4-chloro-beta-nitrostyrene + acetaldehyde = 3-(4-chlorophenyl)-4-nitrobutanal

727187

5.3.2.6

trans-p-chloro-beta-nitrostyrene + isobutanal = 3-(4-chlorophenyl)-2,2-dimethyl-4-nitrobutanal

748503, 749284

5.3.2.6

3 entries

Enzyme Kinetic Parameters

References & Links

Literature References (4)

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Show Reference (4 entries)

BRENDA REFERENCE ID

PUBMED ID

TITLE

YEAR

AUTHORS

JOURNAL

VOLUME

PAGES

727187

23759430

Highly efficient Michael-type addition of acetaldehyde to beta-nitrostyrenes by whole resting cells of Escherichia coli expressing 4-oxalocrotonate tautomerase

2013

Narancic, T.; Radivojevic, J.; Jovanovic, P.; Francuski, D.; Bigovic, M.; Maslak, V.; Savic, V.; Vasiljevic, B.; O'Connor, K.E.; Nikodinovic-Runic, J.

Biores. Technol.

142

462-468

748503

Importance of N-terminal proline for the promiscuous activity of 4-oxalocrotonate tautomerase (4-OT)

2016

Lazic, J.; Spasic, J.; Francuski, D.; Tokic-Vujosevic, Z.; Nikodinovic-Runic, J.; Maslak, V.; Djokic, L.

J. Serb. Chem. Soc.

871-881

748742

26952338

Using mutability landscapes of a promiscuous tautomerase to guide the engineering of enantioselective Michaelases

2016

van der Meer, J.Y.; Poddar, H.; Baas, B.J.; Miao, Y.; Rahimi, M.; Kunzendorf, A.; van Merkerk, R.; Tepper, P.G.; Geertsema, E.M.; Thunnissen, A.M.; Quax, W.J.; Poelarends, G.J.

Nat. Commun.

10911

749284

Synthesis of gamma-nitroaldehydes containing quaternary carbon in the alpha-position using a 4-oxalocrotonate tautomerase whole-cell biocatalyst

2014

Radivojevic, J.; Minovska, G.; Senerovic, L.; OConnor, K.; Jovanovic, P.; Savic, V.; Tokic-Vujosevic, Z.; Nikodinovic-Runic, J.; Maslak, V.

RSC Adv.

60502-60510

Links to other databases for 4-chloro-beta-nitrostyrene

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Show Links (1 entry)

ChEBI

PubChem