Ligand N,N,N',N'-tetramethylethylenediamine
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Basic Ligand Information
C6H16N2
N,N,N',N'-tetramethylethylenediamine
KWYHDKDOAIKMQN-UHFFFAOYSA-N
tetramethylethylenediamine
Roles as Enzyme Ligand
Substrate in Enzyme-catalyzed Reactions (5 results)
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2-nitro-1H-indene-1,3(2H)-dione + Cu(0) + N,N,N',N'-tetramethylethylenediamine + O2 = 1H-indene-1,2,3,-trione + (NO2)CuN,N,N',N'-tetramethylethylenediamine
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ethylnitronate + Cu(0) + N,N,N',N'-tetramethylethylenediamine + O2 = acetone + (NO2)CuN,N,N',N'-tetramethylethylenediamine
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pentane-1-nitronate + Cu(0) + N,N,N',N'-tetramethylethylenediamine + O2 = pentaldehyde + (NO2)CuN,N,N',N'-tetramethylethylenediamine
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propyl-2-nitronate + Cu(0) + N,N,N',N'-tetramethylethylenediamine + O2 = propan-2-one + (NO2)CuN,N,N',N'-tetramethylethylenediamine
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undecan-6-nitronate + Cu(0) + N,N,N',N'-tetramethylethylenediamine + O2 = undecan-6-one + (NO2)CuN,N,N',N'-tetramethylethylenediamine
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Inhibitor in Enzyme-catalyzed Reactions (2 results)
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5 mM, about 50% inhibition
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complete inhibition at 8 mM
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3D Structure of Enzyme-Ligand-Complex (PDB) (6 results)
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Enzyme Kinetic Parameters
References & Links
Literature References (3)
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Copper mediated conversion of nitro compounds to aldehydes or ketones by dioxygen
1996
Balogh-Hergovich, E.; Kaizer, J.; Speier, G.
Chem. Lett.
25
573-574
Purification, characterization, and coal depolymerizing activity of lignin peroxidase from Gloeophyllum sepiarium MTCC-1170
2009
Yadav, M.; Yadav, P.; Yadav, K.D.
Biochemistry
74
1125-1131
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Purification and characterization of novel manganese peroxidase from Schizophyllum commune IBL-06
2013
Asgher, M.; Irshad, M.; Iqbal, H.
Int. J. Agric. Biol.
15
749-754
Links to other databases for N,N,N',N'-tetramethylethylenediamine