Ligand 13-tigloyloxylupanine
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Basic Ligand Information
C20H30N2O3
13-tigloyloxylupanine
UPVPJQNTGLTBPC-YDSNIZARSA-N
13-(2-methylcrotonoyl)oxylupanine, 13-(2-methylcrotonoyl)oxylupinine, 13-tigloyloxylupinine, 13-[(E)-2-methylcrotonoyl]oxylupanine
Related pathways
MetaCyc
lupanine biosynthesis
Roles as Enzyme Ligand
In Vivo Product in Enzyme-catalyzed Reactions (1 result)
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tigloyl-CoA + 13-hydroxylupanine = CoA + 13-tigloyloxylupanine
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Product in Enzyme-catalyzed Reactions (1 result)
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tigloyl-CoA + 13-hydroxylupanine = CoA + 13-tigloyloxylupanine
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Enzyme Kinetic Parameters
References & Links
Literature References (2)
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Enzymatic synthesis of quinolizidine alkaloid esters: a tigloyl-CoA:13-hydroxylupanine O-tigloyl transferase from Lupinus albus L.
1982
Wink, M.; Hartmann, T.
Planta
156
560-565
A novel O-tigloyltransferase for alkaloid biosynthesis in plants. Purification, characterization, and distribution in Lupinus plants
1994
Suzuki, H.; Murakoshi, I.; Saito, K.
J. Biol. Chem.
269
15853-15860
Links to other databases for 13-tigloyloxylupanine