Ligand 12alpha,13alpha-dihydroxyfumitremorgin C

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Basic Ligand Information

Molecular Structure
Picture of 12alpha,13alpha-dihydroxyfumitremorgin C (click for magnification)
Molecular Formula
BRENDA Name
InChIKey
C22H25N3O5
12alpha,13alpha-dihydroxyfumitremorgin C
CPHRCQUGNAGVIB-FWJAZRMLSA-N
Synonyms:
12,13-dihydroxyfumitremorgin C

Show all pahtways known for Show all BRENDA pathways known for 12alpha,13alpha-dihydroxyfumitremorgin C

Roles as Enzyme Ligand

In Vivo Substrate in Enzyme-catalyzed Reactions (1 result)

EC NUMBER
PROVEN IN VIVO REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
dimethylallyl diphosphate + 12alpha,13alpha-dihydroxyfumitremorgin C = diphosphate + fumitremorgin B
show the reaction diagram
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In Vivo Product in Enzyme-catalyzed Reactions (1 result)

EC NUMBER
PROVEN IN VIVO REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
fumitremorgin C + 2 [reduced NADPH-hemoprotein reductase] + 2 O2 = 12alpha,13alpha-dihydroxyfumitremorgin C + 2 [oxidized NADPH-hemoprotein reductase] + 2 H2O
show the reaction diagram
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Substrate in Enzyme-catalyzed Reactions (2 results)

EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
dimethylallyl diphosphate + 12,13-dihydroxyfumitremorgin C = diphosphate + ?
show the reaction diagram
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dimethylallyl diphosphate + 12alpha,13alpha-dihydroxyfumitremorgin C = diphosphate + fumitremorgin B
show the reaction diagram
-

Product in Enzyme-catalyzed Reactions (1 result)

EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
fumitremorgin C + 2 [reduced NADPH-hemoprotein reductase] + 2 O2 = 12alpha,13alpha-dihydroxyfumitremorgin C + 2 [oxidized NADPH-hemoprotein reductase] + 2 H2O
show the reaction diagram
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Enzyme Kinetic Parameters

kcat Value (Turnover Number) (1 result)

EC NUMBER
TURNOVER NUMBER [1/S]
TURNOVER NUMBER MAXIMUM [1/S]
COMMENTARY
LITERATURE
0.03
-
37°C, pH not specified in the publication

KM Value (2 results)

EC NUMBER
KM VALUE [MM]
KM VALUE MAXIMUM [MM]
COMMENTARY
LITERATURE
0.157
-
pH 7.5, 37°C
0.096
-
37°C, pH not specified in the publication

References & Links

Links to other databases for 12alpha,13alpha-dihydroxyfumitremorgin C

ChEBI
PubChem
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PubChem