Ligand undecaprenyl phosphate

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Basic Ligand Information

Molecular Structure
Picture of undecaprenyl phosphate (click for magnification)
Molecular Formula
BRENDA Name
InChIKey
C55H91O4P
undecaprenyl phosphate
UFPHFKCTOZIAFY-NTDVEAECSA-N
Synonyms:
C55-isoprenoid alcohol monophosphate, C55-isoprenyl phosphate, C55-undecaprenyl phosphate, di-trans,poly-cis-undecaprenyl phosphate, ditrans,octacis-undecaprenyl phosphate, ditrans,polycis-undecaprenyl phosphate, ditrans-octacis-undecaprenyl phosphate, ficaprenol phosphate, ficaprenyl phosphate, undecaprenoid-1-ol-phosphate, Undecaprenyl-phosphate, undecaprenyl monophosphate, undecaprenylphosphate


Show all pahtways known for Show all BRENDA pathways known for undecaprenyl phosphate

Roles as Enzyme Ligand

In Vivo Substrate in Enzyme-catalyzed Reactions (13 results)

EC NUMBER
PROVEN IN VIVO REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
GDPmannose + undecaprenyl phosphate = GDP + D-mannosyl-1-phosphoundecaprenol
show the reaction diagram
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UDP-glucose + ficaprenol phosphate = UDP + ficaprenolphosphate-glucose
show the reaction diagram
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UDP-glucose + ditrans,octacis-undecaprenyl phosphate = UMP + alpha-D-glucopyranosyl-diphospho-ditrans,octacis-undecaprenol
show the reaction diagram
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UDP-N-acetyl-alpha-D-galactosamine + ditrans,octacis-undecaprenyl phosphate = UMP + N-acetyl-alpha-D-galactosaminyl-diphospho-ditrans,octacis-undecaprenol
show the reaction diagram
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UDP-4-deoxy-4-formamido-beta-L-arabinopyranose + undecaprenyl phosphate = UDP + 4-deoxy-4-formamido-beta-L-arabinopyranosyl undecaprenyl phosphate
show the reaction diagram
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In Vivo Product in Enzyme-catalyzed Reactions (8 results)

EC NUMBER
PROVEN IN VIVO REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
3-deoxy-alpha-D-manno-oct-2-ulopyranosyl-(2->4)-3-deoxy-alpha-D-manno-oct-2-ulopyranosyl-(2->6)-2-deoxy-2-[[(3R)-3-hydroxypentadecanoyl]amino]-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-[[(3R)-3-hydroxytetradecanoyl]amino]-1-O-phosphono-alpha-D-glucopyranose + 4-amino-4-deoxy-alpha-L-arabinopyranosyl undecaprenyl phosphate = 3-deoxy-alpha-D-manno-oct-2-ulopyranosyl-(2->4)-3-deoxy-alpha-D-manno-oct-2-ulopyranosyl-(2->6)-2-deoxy-2-[[(3R)-3-hydroxypentadecanoyl]amino]-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-(4-amino-4-deoxy-alpha-L-arabinopyranosyl)phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-[[(3R)-3-hydroxytetradecanoyl]amino]-1-O-(4-amino-4-deoxy-alpha-L-arabinopyranosyl)phosphono-alpha-D-glucopyranose + undecaprenyl phosphate
show the reaction diagram
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ATP + undecaprenol = ADP + undecaprenyl phosphate
show the reaction diagram
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Substrate in Enzyme-catalyzed Reactions (49 results)

EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
UDP-glucose + ficaprenyl phosphate = UDP + ficaprenyl beta-D-glucosyl phosphate
show the reaction diagram
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UDP-glucose + ficaprenol phosphate = UDP + ficaprenolphosphate-glucose
show the reaction diagram
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GDP-mannose + C55-undecaprenyl phosphate = GDP + C55-undecaprenyl D-mannosyl phosphate
show the reaction diagram
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UDP-4-deoxy-4-formamido-beta-L-arabinopyranose + ditrans,polycis-undecaprenyl phosphate = UDP + 4-deoxy-4-formamido-alpha-L-arabinopyranosyl ditrans,polycis-undecaprenyl phosphate
show the reaction diagram
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UDP-N-acetyl-alpha-D-galactosamine + ditrans,octacis-undecaprenyl phosphate = UMP + N-acetyl-alpha-D-galactosaminyl-diphospho-ditrans,octacis-undecaprenol
show the reaction diagram
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UDP-4-deoxy-4-formamido-beta-L-arabinopyranose + undecaprenyl phosphate = UDP + 4-deoxy-4-formamido-beta-L-arabinopyranosyl undecaprenyl phosphate
show the reaction diagram
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Product in Enzyme-catalyzed Reactions (15 results)

EC NUMBER
REACTION
REACTION DIAGRAM
LITERATURE
ENZYME 3D STRUCTURE
3-deoxy-alpha-D-manno-oct-2-ulopyranosyl-(2->4)-3-deoxy-alpha-D-manno-oct-2-ulopyranosyl-(2->6)-2-deoxy-2-[[(3R)-3-hydroxypentadecanoyl]amino]-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-[[(3R)-3-hydroxytetradecanoyl]amino]-1-O-phosphono-alpha-D-glucopyranose + 4-amino-4-deoxy-alpha-L-arabinopyranosyl undecaprenyl phosphate = 3-deoxy-alpha-D-manno-oct-2-ulopyranosyl-(2->4)-3-deoxy-alpha-D-manno-oct-2-ulopyranosyl-(2->6)-2-deoxy-2-[[(3R)-3-hydroxypentadecanoyl]amino]-3-O-[(3R)-3-hydroxytetradecanoyl]-4-O-(4-amino-4-deoxy-alpha-L-arabinopyranosyl)phosphono-beta-D-glucopyranosyl-(1->6)-2-deoxy-3-O-[(3R)-3-hydroxytetradecanoyl]-2-[[(3R)-3-hydroxytetradecanoyl]amino]-1-O-(4-amino-4-deoxy-alpha-L-arabinopyranosyl)phosphono-alpha-D-glucopyranose + undecaprenyl phosphate
show the reaction diagram
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CTP + ficaprenol = CDP + ficaprenyl phosphate
show the reaction diagram
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undecaprenyldiphosphate + H2O = undecaprenylphosphate + phosphate
show the reaction diagram
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Activator in Enzyme-catalyzed Reactions (1 result)

EC NUMBER
COMMENTARY
LITERATURE
ENZYME 3D STRUCTURE
stimulates exchange reaction
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Inhibitor in Enzyme-catalyzed Reactions (1 result)

EC NUMBER
COMMENTARY
LITERATURE
ENZYME 3D STRUCTURE
inhibits in excess amount
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Enzyme Kinetic Parameters

kcat Value (Turnover Number) (18 results)

EC NUMBER
TURNOVER NUMBER [1/S]
TURNOVER NUMBER MAXIMUM [1/S]
COMMENTARY
LITERATURE
1.2
-
pH 8, 65°C

KM Value (21 results)

EC NUMBER
KM VALUE [MM]
KM VALUE MAXIMUM [MM]
COMMENTARY
LITERATURE
0.02
0.04
-
0.00117
-
-
0.12
-
pH 8, 65°C
0.0785
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in 50 mM Tris-HCl (pH 8.5), 25 mM MgCl2, 1% (w/v) CHAPS, at 37°C

References & Links

Links to other databases for undecaprenyl phosphate

ChEBI
PubChem
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PubChem