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Substrate and cofactor reactivity of a carbon monoxide dehydrogenase-corrinoid enzyme complex: stepwise reduction of iron-sulfur and corrinoid centers, the corrinoid Co2+/1+ redox midpoint potential, and overall synthesis of acetyl-CoA
1993
Grahame, D.A.
Biochemistry
32
10786-10793
Catalysis of acetyl-CoA cleavage and tetrahydrosarcinapterin methylation by a carbon monoxide dehydrogenase-corrinoid enzyme complex
1991
Grahame, D.A.
J. Biol. Chem.
266
22227-22233
Reductive activation of the coenzyme A/acetyl-CoA isotopic exchange reaction catalyzed by carbon monoxide dehydrogenase from Clostridium thermoaceticum and its inhibition by nitrous oxide and carbon monoxide
1991
Lu, W.P.; Ragsdale, S.W.
J. Biol. Chem.
266
3554-3564
Acetyl-coenzyme A synthesis from methyltetrahydrofolate, CO, and coenzyme A by enzymes purified from Clostridium thermoaceticum: Attainment of in vivo rates and identification of rate-limiting steps
1992
Roberts, J.R.; Lu, W.P.; Ragsdale, S.W.
J. Bacteriol.
174
4667-4676
Role of the [4Fe-4S] cluster in reductive activation of the cobalt center of the corrinoid iron-sulfur protein from Clostridium thermoaceticum during acetate biosynthesis
1998
Menon, S.; Ragsdale, S.W.
Biochemistry
37
5689-5698
Controlled potential enzymology of methyl transfer reactions involved in acetyl-CoA synthesis by CO dehydrogenase and the corrinoid/iron-sulfur protein from Clostridium thermoaceticum
1990
Lu, W.P.; Harder, S.R.; Ragsdale, S.W.
J. Biol. Chem.
265
3124-3133
Anaerobic pathway for conversion of the methyl group of aromatic methyl ethers to acetic acid by Clostridium thermoaceticum
1994
Kasmi, A.E.; Rajasekharan, S.; Ragsdale, S.W.
Biochemistry
33
11217-11224
The role of an iron-sulfur cluster in an enzymic methylation reaction: Methylation of CO dehydrogenase/acetyl-CoA synthase by the methylated corrinoid iron-sulfur protein
1999
Menon, S.; Ragsdale, S.W.
J. Biol. Chem.
274
11513-11518
Evidence for intersubunit communication during acetyl-CoA cleavage by the multienzyme CO dehydrogenase/acetyl-CoA synthase complex from Methanosarcina thermophila. Evidence that the beta subunit catalyzes C-C and C-S bond cleavage
2000
Murakami, E.; Ragsdale, S.W.
J. Biol. Chem.
275
4699-4707
Inactivation of acetyl-CoA synthase/carbon monoxide dehydrogenase by copper
2003
Bramlett, M.R.; Tan, X.; Lindahl, P.A.
J. Am. Chem. Soc.
125
9316-9317
Acetyl Coenzyme A synthesis from unnatural methylated corrinoids: Requirement for "Base-Off" coordination at cobalt
2001
Seravalli, J.; Brown, K.L.; Ragsdale, S.W.
J. Am. Chem. Soc.
123
1786-1787
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