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Information on EC 5.5.1.22 - (-)-bornyl diphosphate synthase

for references in articles please use BRENDA:EC5.5.1.22

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IUBMB Comments

Requires Mg2+. The enzyme from Tanacetum vulgare (tansy) can also use (3S)-linalyl diphosphate or more slowly neryl diphosphate in vitro. The reaction proceeds via isomeration of geranyl diphosphate to (3S)-linalyl diphosphate . The oxygen and phosphorus originally linked to C-1 of geranyl diphosphate end up linked to C-2 of (–)-bornyl diphosphate . cf. EC 5.5.1.8 (+)-bornyl diphosphate synthase.

The enzyme appears in viruses and cellular organisms

Synonyms
(-)-bornyl pyrophosphate cyclase, (-)-BPP cyclase, bornyl pyrophosphate synthase, bornyl pyrophosphate synthetase, more

REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
geranyl diphosphate = (-)-bornyl diphosphate
show the reaction diagram
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PATHWAY SOURCE
PATHWAYS
MetaCyc
(-)-camphor biosynthesis
Highest Expressing Human Cell Lines
Cell Line Links Gene Links