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Information on EC 5.4.4.6 - 9,12-octadecadienoate 8-hydroperoxide 8S-isomerase

for references in articles please use BRENDA:EC5.4.4.6
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IUBMB Comments
The enzyme contains heme. The bifunctional enzyme from Gaeumannomyces graminis catalyses the oxidation of linoleic acid to (8R,9Z,12Z)-8-hydroperoxyoctadeca-9,12-dienoate (cf. EC 1.13.11.60, linoleate 8R-lipoxygenase), which is then isomerized to (7S,8S,9Z,12Z)-5,8-dihydroxyoctadeca-9,12-dienoate .
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The enzyme appears in viruses and cellular organisms
Synonyms
7,8-diol synthase, 7,8-LDS, 7,8-linoleate diol synthase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
(8R,9Z,12Z)-8-hydroperoxyoctadeca-9,12-dienoate = (7S,8S,9Z,12Z)-7,8-dihydroxyoctadeca-9,12-dienoate
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PATHWAY SOURCE
PATHWAYS
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