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IUBMB Comments Involved in the biosynthesis of menthol and related monoterpenes in peppermint (Mentha piperita ) leaves.
Synonyms
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Isomerase, isopiperitenone
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Isopiperitenone isomerase
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Isopiperitenone = piperitenone
Isopiperitenone = piperitenone
double bond migration catalyzed by this enzyme involves an intramolecular 1,3-hydrogen transfer
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Isopiperitenone = piperitenone
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intramolecular oxidoreduction
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isopiperitenone DELTA8-DELTA4-isomerase
Involved in the biosynthesis of menthol and related monoterpenes in peppermint (Mentha piperita) leaves.
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Isopiperitenone
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Substrates: key step in the metabolic pathway for the conversion of the initially formed cyclic olefin (+/-)-limonene, to (-)-menthol and related monoterpenes characteristic of peppermint
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Isopiperitenone
Piperitenone
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Substrates: -
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Isopiperitenone
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Substrates: key step in the metabolic pathway for the conversion of the initially formed cyclic olefin (+/-)-limonene, to (-)-menthol and related monoterpenes characteristic of peppermint
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p-hydroxymercuribenzoate
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7 - 9
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half-maximal activities at pH 7 and 9
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brenda
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brenda
Highest Expressing Human Cell Lines
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stable to dialysis at pH 5.5-9.5
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Kjonaas, R.B.; Venkatachalam, K.V.; Croteau, R.
Metabolism of monoterpenes: oxidation of isopiperitenol to isopiperitenone, and subsequent isomerization to piperitenone by soluble enzyme preparations from peppermint (Mentha piperita) leaves
Arch. Biochem. Biophys.
238
49-60
1985
Mentha x piperita
brenda
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