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Information on EC 4.8.1.2 - aliphatic aldoxime dehydratase

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EC Tree
     4 Lyases
         4.8 Nitrogen-oxygen lyases
             4.8.1 Hydro-lyases
                4.8.1.2 aliphatic aldoxime dehydratase
IUBMB Comments
The enzyme from Pseudomonas chlororaphis contains Ca2+ and protoheme IX, the iron of which must be in the form Fe(II) for activity. The enzyme exhibits a strong preference for aliphatic aldoximes, such as butyraldoxime and acetaldoxime, over aromatic aldoximes, such as pyridine-2-aldoxime, which is a poor substrate. No activity was found with the aromatic aldoximes benzaldoxime and pyridine-4-aldoxime.
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Word Map
The enzyme appears in viruses and cellular organisms
Synonyms
aldoxime dehydratase, oxdre, aliphatic aldoxime dehydratase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
an aliphatic aldoxime = an aliphatic nitrile + H2O
show the reaction diagram
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