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Information on EC 4.2.3.97 - (-)-delta-cadinene synthase

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EC Tree
     4 Lyases
         4.2 Carbon-oxygen lyases
             4.2.3 Acting on phosphates
                4.2.3.97 (-)-delta-cadinene synthase
IUBMB Comments
The cyclization mechanism involves an intermediate nerolidyl diphosphate leading to a helminthogermacradienyl cation. Following a 1,3-hydride shift of the original 1-pro-S hydrogen of (2E,6E)-farnesyl diphosphate, cyclization and deprotonation gives (-)-delta-cadinene.
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The enzyme appears in viruses and cellular organisms
Synonyms
SCreLAV_p0328, sscg_02150, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
(2E,6E)-farnesyl diphosphate = (-)-delta-cadinene + diphosphate
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