Dictyostelium discoideum
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IUBMB Comments Isolated from the slime mould Dictyostelium discoideum . The 1-proR hydrogen atom of geranylgeranyl diphosphate is lost in the reaction.
The expected taxonomic range for this enzyme is: Dictyostelium discoideum
Synonyms PCS, more
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geranylgeranyl diphosphate = beta-pinacene + diphosphate
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geranylgeranyl-diphosphate diphosphate-lyase (cyclizing, beta-pinacene-forming)
Isolated from the slime mould Dictyostelium discoideum. The 1-proR hydrogen atom of geranylgeranyl diphosphate is lost in the reaction.
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geranylgeranyl diphosphate
beta-pinacene + diphosphate
geranylgeranyl diphosphate
beta-pinacene + diphosphate
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Substrates: - Products: -
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geranylgeranyl diphosphate
beta-pinacene + diphosphate
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Substrates: beta-pinacene i.e. 4,8,12-trimethyl-1-(propan-2-yl)cyclotetradeca-1,3,7,11-tetraene. The 1-proR hydrogen atom of geranylgeranyl diphosphate is lost in the reaction Products: -
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geranylgeranyl diphosphate
beta-pinacene + diphosphate
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Substrates: - Products: -
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TPS5_DICDI
347
0
40373
Swiss-Prot
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Rinkel, J.; Rabe, P.; Chen, X.; Koellner, T.G.; Chen, F.; Dickschat, J.S.
Mechanisms of the diterpene cyclases beta-pinacene synthase from Dictyostelium discoideum and hydropyrene synthase from Streptomyces clavuligerus
Chemistry
23
10501-10505
2017
Dictyostelium discoideum
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