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Information on EC 4.2.3.164 - (+)-eremophilene synthase for references in articles please use BRENDA:EC4.2.3.164
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EC Tree
IUBMB Comments The enzyme has been identified in the myxobacterium Sorangium cellulosum and in the fungus Fusarium fujikuroi.
The expected taxonomic range for this enzyme is: Eukaryota, Bacteria
Synonyms
geoA, STC3,
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geoA
gene name
STC3
gene name
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(2E,6E)-farnesyl diphosphate = (+)-eremophilene + diphosphate
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(2E,6E)-farnesyl-diphosphate diphosphate-lyase (cyclizing, (+)-eremophilene-forming)
The enzyme has been identified in the myxobacterium Sorangium cellulosum and in the fungus Fusarium fujikuroi.
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(2E,6E)-farnesyl diphosphate
(+)-eremophilene + diphosphate
(2E,6E)-farnesyl diphosphate
(+)-eremophilene + diphosphate
(+)-eremophilene i.e. (3S,4aS,5R)-4a,5-dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydronaphthalene. Mechanistic characterization by isotopic labelling techniques. No activity with geranylgeranyl diphosphate and geranyl diphosphate
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(2E,6E)-farnesyl diphosphate
(+)-eremophilene + diphosphate
(+)-eremophilene i.e. (3S,4aS,5R)-4a,5-dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydronaphthalene. Mechanistic characterization by isotopic labelling techniques. No activity with geranylgeranyl diphosphate and geranyl diphosphate
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(2E,6E)-farnesyl diphosphate
(+)-eremophilene + diphosphate
the enzyme is involved in the biosynthesis of (+)-eremophilene derivatives
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(2E,6E)-farnesyl diphosphate
(+)-eremophilene + diphosphate
(+)-eremophilene i.e. (3S,4aS,5R)-4a,5-dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydronaphthalene
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(2E,6E)-farnesyl diphosphate
(+)-eremophilene + diphosphate
the enzyme is involved in the biosynthesis of (+)-eremophilene derivatives
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?
(2E,6E)-farnesyl diphosphate
(+)-eremophilene + diphosphate
(+)-eremophilene i.e. (3S,4aS,5R)-4a,5-dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydronaphthalene
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(2E,6E)-farnesyl diphosphate
(+)-eremophilene + diphosphate
(2E,6E)-farnesyl diphosphate
(+)-eremophilene + diphosphate
A9FZ87
the enzyme is involved in the biosynthesis of (+)-eremophilene derivatives
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(2E,6E)-farnesyl diphosphate
(+)-eremophilene + diphosphate
A9FZ87
the enzyme is involved in the biosynthesis of (+)-eremophilene derivatives
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?
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UniProt
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UniProt
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UniProt
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UniProt
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EREMS_GIBF5
Gibberella fujikuroi (strain CBS 195.34 / IMI 58289 / NRRL A-6831)
357
0
40971
Swiss-Prot
EREMS_SORC5
Sorangium cellulosum (strain So ce56)
329
0
38073
Swiss-Prot
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40000
x * 40000, SDS-PAGE
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x * 40000, SDS-PAGE
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x * 40000, SDS-PAGE
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expression in Escherichia coli
overexpression in Escherichia coli
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Burkhardt, I.; Siemon, T.; Henrot, M.; Studt, L.; Rosler, S.; Tudzynski, B.; Christmann, M.; Dickschat, J.S.
Mechanistic Characterisation of two sesquiterpene cyclases from the plant pathogenic fungus Fusarium fujikuroi
Angew. Chem. Int. Ed. Engl.
55
8748-8751
2016
Fusarium fujikuroi (S0DX56), Fusarium fujikuroi NRRL A-6831 (S0DX56)
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Schifrin, A.; Ly, T.T.; Gunnewich, N.; Zapp, J.; Thiel, V.; Schulz, S.; Hannemann, F.; Khatri, Y.; Bernhardt, R.
Characterization of the gene cluster CYP264B1-geoA from Sorangium cellulosum So ce56: biosynthesis of (+)-eremophilene and its hydroxylation
Chembiochem
16
337-344
2015
Sorangium cellulosum (A9FZ87), Sorangium cellulosum, Sorangium cellulosum So ce56 (A9FZ87), Sorangium cellulosum So ce56
brenda
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4.2.3.164 (+)-eremophilene synthase
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