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Information on EC 4.2.3.115 - alpha-terpinene synthase

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EC Tree
     4 Lyases
         4.2 Carbon-oxygen lyases
             4.2.3 Acting on phosphates
                4.2.3.115 alpha-terpinene synthase
IUBMB Comments
The enzyme has been characterized from Dysphania ambrosioides (American wormseed). Requires Mg2+. Mn2+ is less effective. The enzyme will also use (3R)-linalyl diphosphate. The reaction involves a 1,2-hydride shift. The 1-pro-S hydrogen of geranyl diphosphate is lost.
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The enzyme appears in viruses and cellular organisms
Synonyms
CoTPS1, TPS1, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
geranyl diphosphate = alpha-terpinene + diphosphate
show the reaction diagram
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