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Information on EC 4.2.3.114 - gamma-terpinene synthase

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EC Tree
     4 Lyases
         4.2 Carbon-oxygen lyases
             4.2.3 Acting on phosphates
                4.2.3.114 gamma-terpinene synthase
IUBMB Comments
Isolated from Thymus vulgaris (thyme) [1,2], Citrus limon (lemon) , Citrus unshiu (satsuma) and Origanum vulgare (oregano) . Requires Mg2+. Mn2+ less effective. The reaction involves a 1,2-hydride shift. The 5-pro-S hydrogen of geranyl diphosphate is lost. Traces of several other monoterpenoids are formed in addition to gamma-terpinene.
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Word Map
The enzyme appears in viruses and cellular organisms
Synonyms
CitMTSL61, ClcTS, Os04g27790, OsTPS24, OvTPS2, RPS2, terpene synthase 24, TPS1, TPS2, TPS4, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
geranyl diphosphate = gamma-terpinene + diphosphate
show the reaction diagram
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