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Information on EC 4.2.3.111 - (-)-alpha-terpineol synthase for references in articles please use BRENDA:EC4.2.3.111Please wait a moment until all data is loaded. This message will disappear when all data is loaded.
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The expected taxonomic range for this enzyme is: Vitis vinifera
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(-)-alpha-terpineol synthase
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geranyl diphosphate + H2O = (-)-alpha-terpineol + diphosphate
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Monoterpenoid biosynthesis
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Biosynthesis of secondary metabolites
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geranyl-diphosphate diphosphate-lyase [cyclizing, (-)-alpha-terpineol-forming]
The enzyme has been characterized from Vitis vinifera (grape). Also forms some 1,8-cineole and traces of other monoterpenoids.
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UniProt
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geranyl diphosphate
(-)-alpha-terpineol + diphosphate
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products are 50.1% (-)-alpha-terpineol, 11.8% 1,8-cineole, 8.5% (+)-beta-pinene, plus lower amounts of additional monoterpenes
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no substrates: farnesyl diphosphate, geranylgeranyl diphosphate
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no substrates: farnesyl diphosphate, geranylgeranyl diphosphate
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strongest signals with RNA from flower buds and strongly reduced transcript levels in pre- and postanthesis open flowers and in set flowers at early fruit onset
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additional information
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expression appears restricted to flowers
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expression in Escherichia coli
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ATESY_MAGGA
592
67904
Swiss-Prot
ATESY_VITVI
590
68883
Swiss-Prot
PT10_PINTA
627
71884
Swiss-Prot
A0A2G9HSG2_9LAMI
413
48964
TrEMBL
A0A2G9GL89_9LAMI
603
69831
TrEMBL
A0A2G9GEB1_9LAMI
574
67567
TrEMBL
A0A2G9HM99_9LAMI
600
70742
TrEMBL
V5JYL0_THYVU
597
69178
TrEMBL
A0A2G9HSN5_9LAMI
600
70609
TrEMBL
A0A2G9HPL9_9LAMI
603
69872
TrEMBL
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Luecker, J.; Bowen, P.; Bohlmann, J.
Vitis vinifera terpenoid cyclases: functional identification of two sesquiterpene synthase cDNAs encoding (+)-valencene synthase and (-)-germacrene D synthase and expression of mono- and sesquiterpene synthases in grapevine flowers and berries
Phytochemistry
65
2649-2659
2004
Vitis vinifera
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Martin, D.M.; Bohlmann, J.
Identification of Vitis vinifera (-)-alpha-terpineol synthase by in silico screening of full-length cDNA ESTs and functional characterization of recombinant terpene synthase
Phytochemistry
65
1223-1229
2004
Vitis vinifera, Vitis vinifera (Q6PWU2)
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