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The expected taxonomic range for this enzyme is: Ranunculus acris
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(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate = (9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O
(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate = (9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O
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(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate = (9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O
stereospecific removal of the pro-S hydrogen and retention of the pro-R hydrogen
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(9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid synthase
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(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate
(9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O
(9Z,11E,13S,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate
(9Z,11E)-12-[(1Z,3Z)-hexa-1,3-dien-1-yloxy]dodeca-9,11-dienoic acid + H2O
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no activity with (9Z,11E,13R,15Z)-13-hydroperoxy-9,11,15-octadecatrienoate
i.e. omega5(Z)-etherolenic acid
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additional information
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no activity with (9S)-hydroperoxides
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(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate
(9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O
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i.e. omega5(Z)-etheroleic acid
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(9Z,11E,13S)-13-hydroperoxy-9,11-octadecadienoate
(9Z,11E)-12-[(1Z)-hex-1-en-1-yloxy]dodeca-9,11-dienoic acid + H2O
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stereospecific removal of the pro-S hydrogen and retention of the pro-R hydrogen
i.e. omega5(Z)-etheroleic acid
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brenda
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brenda
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physiological function
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the enzyme is involved in the pathway for biosynthesis of divinyl ether fatty acids in green leaves of Ranunculus acris
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Hamberg, M.
A pathway for biosynthesis of divinyl ether fatty acids in green leaves
Lipids
33
1061-1071
1998
Ranunculus acris
brenda
Hamberg, M.
Biosynthesis of new divinyl ether oxylipins in Ranunculus plants
Lipids
37
427-433
2002
Ranunculus acris
brenda
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Enzyme Nomenclature
4.2.1.B5 omega5(Z)-etheroleic acid synthase
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