The mechanism appears to involve hydration of the acetylene and decarboxylation of the oxaloacetic acid formed, although free oxaloacetate is not an intermediate. It is thus analogous to EC 4.2.1.27 (acetylenecarboxylate hydratase) in its mechanism.
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The expected taxonomic range for this enzyme is: Pseudomonas sp.
Synonyms
acetylenedicarboxylate hydrase, EC 4.2.1.72, hydratase, acetylenedicarboxylate, more
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REACTION
REACTION DIAGRAM
COMMENTARY
ORGANISM
UNIPROT
LITERATURE
acetylenedicarboxylate + H2O = pyruvate + CO2
the mechanism appears to involve hydration of the acetylene and decarboxylation of the oxaloacetic acid formed, although free oxaloacetate is not an intermediate. It is thus analogous to EC 4.2.1.71, acetylenecarboxylate hydratase, in its mechanism. Formerly EC 4.2.1.72
The mechanism appears to involve hydration of the acetylene and decarboxylation of the oxaloacetic acid formed, although free oxaloacetate is not an intermediate. It is thus analogous to EC 4.2.1.27 (acetylenecarboxylate hydratase) in its mechanism.
Enzymatic utilization of acetylenic compounds. I. An enzyme converting acetylenedicarboxylic acid to pyruvate
J. Biol. Chem.
233
706-711
1958
no activity in Clostridium cylindrosporum, no activity in Clostridium kluyveri, no activity in Escherichia coli, no activity in Pseudomonas fluorescens, no activity in Rattus norvegicus, Pseudomonas sp.
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History
4.1.1.78 acetylenedicarboxylate decarboxylase
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