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ATP + (2R)-2-amino-2-[5-(4-octylphenyl)-1H-imidazol-2-yl]propan-1-ol
ADP + (2R)-2-amino-2-[5-(4-octylphenyl)-1H-imidazol-2-yl]propyl dihydrogen phosphate
ATP + (2R)-2-amino-4-(4-heptoxyphenyl)-2-methylbutan-1-ol
ADP + (2R)-2-amino-4-(4-heptoxyphenyl)-2-methylbutyl dihydrogen phosphate
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Substrates: isoform SPHK2 is 6fold more efficient than SPHK1 in phosphorylating
Products: product is a nanomolar agonist of sphingosine 1-phsphate receptor 1, whereas the (2S)-enantiomer is much weaker
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ATP + (2R,3R)-3-amino-5-(4-heptoxyphenyl)-3-methylpentan-2-ol
ADP + (2R,3R)-3-amino-5-(4-heptoxyphenyl)-3-methylpentan-2-yl dihydrogen phosphate
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Substrates: no substrate for SPHK1, phosphorylated by SPHK2 at low rates
Products: product is a potent agonist of sphingosine 1-phsphate receptor 1
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ATP + 1-O-hexadecyl-2-deoxy-2-amino-sn-glycerol
ADP + 1-O-hexadecyl-2-deoxy-2-amino-sn-glycerol 3-phosphate
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Substrates: isozyme SPHK2, 10fold lower activity with isozyme SPHK1
Products: -
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ATP + 2-amino-2-[4-(4-octylphenyl)-1,3-oxazol-2-yl]propan-1-ol
ADP + 2-amino-2-[4-(4-octylphenyl)-1,3-oxazol-2-yl]propyl dihydrogen phosphate
ATP + 2-amino-2-[5-(4-octylphenyl)-1,2,4-oxadiazol-3-yl]propan-1-ol
ADP + 2-amino-2-[5-(4-octylphenyl)-1,2,4-oxadiazol-3-yl]propyl dihydrogen phosphate
ATP + 4,8-sphingadienine
ADP + 4,8-sphingadienine 1-phosphate
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Substrates: high activity
Products: -
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ATP + 7-nitro-2-1,3-benzoxadiazol-4-yl-labeled sphingosine
ADP + 7-nitro-2-1,3-benzoxadiazol-4-yl-labeled sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + biotinyl-D-erythro-sphingosine
ADP + biotinyl-D-erythro-sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + D-(+)-erythro-sphinganine
ADP + D-(+)-erythro-sphinganine 1-phosphate
ATP + D-erythro-dihydrosphingosine
ADP + D-erythro-dihydrosphingosine 1-phosphate
Substrates: the activity of longrSK1 towards dihydrosphingosine is about 3.6fold higher than that of rSK1
Products: -
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ATP + D-erythro-sphingosine
ADP + D-erythro-sphingosine 1-phosphate
ATP + DELTA4-unsaturated long chain sphingosine
ADP + DELTA4-unsaturated long chain sphingosine 1-phosphate
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Substrates: high activity
Products: -
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ATP + dihydrosphingosine
ADP + dihydrosphingosine 1-phosphate
ATP + DL-erythro-dihydrosphingosine
ADP + DL-erythro-dihydrosphingosine 1-phosphate
Substrates: -
Products: -
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ATP + DL-threo-dihydrosphingosine
ADP + DL-threo-dihydrosphingosine 1-phosphate
ATP + fluorescein-labeled sphingosine
ADP + fluorescein-labeled sphingosine 1-phosphate
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Substrates: -
Products: -
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ATP + FTY720
ADP + ?
Substrates: -
Products: -
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ATP + FTY720
ADP + FTY720 1-phosphate
ATP + L-(-)-threo-sphinganine
ADP + L-(-)-threo-sphinganine 1-phosphate
-
Substrates: -
Products: -
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ATP + N-[7-(4-nitrobenzo-2-oxa-1,3-diazole)]-6-aminocaproyl-D-erythro-sphingosine
ADP + N-[7-(4-nitrobenzo-2-oxa-1,3-diazole)]-6-aminocaproyl-D-erythro-sphingosine 1-phosphate
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Substrates: -
Products: -
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ATP + NBD-sphingosine
ADP + NBD-sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + phytosphingosine
ADP + phytosphingosine 1-phosphate
ATP + sphinganine
ADP + sphinganine 1-phosphate
ATP + sphingosine
ADP + sphingosine 1-phosphate
ATP + sphingosine-fluorescin
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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GTP + sphinganine
GDP + sphinganine 1-phosphate
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Substrates: isozyme SPHK1
Products: -
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additional information
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ATP + (2R)-2-amino-2-[5-(4-octylphenyl)-1H-imidazol-2-yl]propan-1-ol
ADP + (2R)-2-amino-2-[5-(4-octylphenyl)-1H-imidazol-2-yl]propyl dihydrogen phosphate
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Substrates: approximately 20% the activity of sphingosine at isoformSPHK2
Products: product is a sphingosine 1-phosphate receptor prodrug
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ATP + (2R)-2-amino-2-[5-(4-octylphenyl)-1H-imidazol-2-yl]propan-1-ol
ADP + (2R)-2-amino-2-[5-(4-octylphenyl)-1H-imidazol-2-yl]propyl dihydrogen phosphate
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Substrates: -
Products: product is a sphingosine 1-phosphate receptor prodrug
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ATP + 2-amino-2-[4-(4-octylphenyl)-1,3-oxazol-2-yl]propan-1-ol
ADP + 2-amino-2-[4-(4-octylphenyl)-1,3-oxazol-2-yl]propyl dihydrogen phosphate
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Substrates: good substrate of isoform SPHK2
Products: product is a sphingosine 1-phosphate receptor prodrug
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ATP + 2-amino-2-[4-(4-octylphenyl)-1,3-oxazol-2-yl]propan-1-ol
ADP + 2-amino-2-[4-(4-octylphenyl)-1,3-oxazol-2-yl]propyl dihydrogen phosphate
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Substrates: -
Products: product is a sphingosine 1-phosphate receptor prodrug
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ATP + 2-amino-2-[5-(4-octylphenyl)-1,2,4-oxadiazol-3-yl]propan-1-ol
ADP + 2-amino-2-[5-(4-octylphenyl)-1,2,4-oxadiazol-3-yl]propyl dihydrogen phosphate
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Substrates: moderate activity at isoform SPHK2, it is the only alcohol in the series to have significant activity at isoform SPHK1
Products: product is a sphingosine 1-phosphate receptor prodrug
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ATP + 2-amino-2-[5-(4-octylphenyl)-1,2,4-oxadiazol-3-yl]propan-1-ol
ADP + 2-amino-2-[5-(4-octylphenyl)-1,2,4-oxadiazol-3-yl]propyl dihydrogen phosphate
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Substrates: -
Products: product is a sphingosine 1-phosphate receptor prodrug
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ATP + D-(+)-erythro-sphinganine
ADP + D-(+)-erythro-sphinganine 1-phosphate
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Substrates: -
Products: -
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ATP + D-(+)-erythro-sphinganine
ADP + D-(+)-erythro-sphinganine 1-phosphate
Substrates: -
Products: -
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ATP + D-(+)-erythro-sphinganine
ADP + D-(+)-erythro-sphinganine 1-phosphate
-
Substrates: -
Products: -
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ATP + D-(+)-erythro-sphinganine
ADP + D-(+)-erythro-sphinganine 1-phosphate
-
Substrates: -
Products: -
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ATP + D-erythro-sphingosine
ADP + D-erythro-sphingosine 1-phosphate
-
Substrates: -
Products: -
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ATP + D-erythro-sphingosine
ADP + D-erythro-sphingosine 1-phosphate
-
Substrates: -
Products: -
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ATP + D-erythro-sphingosine
ADP + D-erythro-sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + D-erythro-sphingosine
ADP + D-erythro-sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + D-erythro-sphingosine
ADP + D-erythro-sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + D-erythro-sphingosine
ADP + D-erythro-sphingosine 1-phosphate
Substrates: -
Products: nucleotide binding in the cleft between the N-terminal domain and C-terminal domain
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ATP + D-erythro-sphingosine
ADP + D-erythro-sphingosine 1-phosphate
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Substrates: major substrate of isozyme SPHK1, also active with isozyme SPHK2
Products: -
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ATP + D-erythro-sphingosine
ADP + D-erythro-sphingosine 1-phosphate
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Substrates: -
Products: -
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ATP + D-erythro-sphingosine
ADP + D-erythro-sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + D-erythro-sphingosine
ADP + D-erythro-sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + dihydrosphingosine
ADP + dihydrosphingosine 1-phosphate
Substrates: -
Products: -
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ATP + dihydrosphingosine
ADP + dihydrosphingosine 1-phosphate
Substrates: C14 and C16 dihydrosphingosine substrates
Products: -
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ATP + DL-threo-dihydrosphingosine
ADP + DL-threo-dihydrosphingosine 1-phosphate
Substrates: -
Products: -
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ATP + DL-threo-dihydrosphingosine
ADP + DL-threo-dihydrosphingosine 1-phosphate
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Substrates: isozyme SPHK2, no activity with isozyme SPHK1
Products: -
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ATP + FTY720
ADP + FTY720 1-phosphate
Substrates: immunomodulatory drug, high activity with isozyme SPHK2, 7fold lower activity with isozyme SPHK1
Products: -
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ATP + FTY720
ADP + FTY720 1-phosphate
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Substrates: FTY720 is stereoselectively phosphorylated to the active principle (S)-FTY720-phosphate which binds to four of the five known sphingosine-1-phosphate receptors. The introduction of a second stereocenter in the amino alcohol head group of FTY720-like compounds has a strong effect on the phosphorylation efficiency and selectivity by SPHKs and on transiently decreasing peripheral lymphocyte counts in vivo
Products: -
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ATP + FTY720
ADP + FTY720 1-phosphate
Substrates: immunomodulatory drug, high activity with isozyme SPHK2, lower activity with isozyme SPHK1
Products: -
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ATP + phytosphingosine
ADP + phytosphingosine 1-phosphate
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Substrates: phytosphingosine 1-phosphate is capable of regulating the turgor in guard cells/stomatal aperture via G-proteins
Products: -
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ATP + phytosphingosine
ADP + phytosphingosine 1-phosphate
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Substrates: i.e. 4-hydroxysphinganine, moderate or low activity
Products: -
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ATP + phytosphingosine
ADP + phytosphingosine 1-phosphate
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Substrates: -
Products: -
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ATP + phytosphingosine
ADP + phytosphingosine 1-phosphate
Substrates: -
Products: -
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ATP + phytosphingosine
ADP + phytosphingosine 1-phosphate
-
Substrates: low activity
Products: -
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ATP + phytosphingosine
ADP + phytosphingosine 1-phosphate
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Substrates: isozyme SPHK2, no activity with isozyme SPHK1
Products: -
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ATP + phytosphingosine
ADP + phytosphingosine 1-phosphate
-
Substrates: -
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
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Substrates: i.e. dihydrosphingosine, moderate or low activity
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
-
Substrates: -
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
Substrates: -
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
Substrates: -
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
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Substrates: involved in signal transduction in the nucleus
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
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Substrates: the lipid phosphate acts as a pleiotropic agent in cell signalling pathways, acts often in concert with ceramide 1-phosphate, enzyme is involved in the sphingomyelid pathway, overview
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
Substrates: 2fold higher activity with isozyme SPHK1 compared to isozyme SPHK2
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
Substrates: SK2 has a higher substrate affinity to sphinganine than to sphingosine
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
-
Substrates: overview on cellular functions
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
-
Substrates: -
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
Substrates: -
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
Substrates: -
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
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Substrates: involved in regulation of GTP cyclohydrolase I and 6(r)-5,6,7,8-tetrahydrobiopterin
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
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Substrates: the lipid phosphate acts as a pleiotropic agent in cell signalling pathways, enzyme is involved in the sphingomyelid pathway, overview
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
plant
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Substrates: overview on cellular functions
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
-
Substrates: -
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
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Substrates: D-erythro-sphinganine, sphingosine metabolism
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
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Substrates: calcium mobilization through antigen receptors utilizes enzyme
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
-
Substrates: overview on cellular functions
Products: -
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ATP + sphinganine
ADP + sphinganine 1-phosphate
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Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
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Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
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Substrates: -
Products: sphingosine 1-phosphate is a potent bioactive sphingolipid, sphingolipid metabolism, overview
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ATP + sphingosine
ADP + sphingosine 1-phosphate
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Substrates: sphingosine 1-phosphate is capable of regulating the turgor in guard cells/stomatal aperture via G-proteins
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
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Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
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Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
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Substrates: -
Products: sphingosine 1-phosphate is a potent bioactive sphingolipid, sphingolipid metabolism, overview
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ATP + sphingosine
ADP + sphingosine 1-phosphate
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Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
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Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
-
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
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Substrates: -
Products: sphingosine 1-phosphate is a potent bioactive sphingolipid, sphingolipid metabolism, overview
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: C14 and C16 sphingosine substrates
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
-
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
-
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
-
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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ATP + sphingosine
ADP + sphingosine 1-phosphate
Substrates: -
Products: -
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