Streptomyces sp. NCIMB40513
A0A3T0ZHH3
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IUBMB Comments The enzyme, characterized from the bacterium Streptomyces sioyaensis , catalyses the last step in the biosynthesis of the monoterpene alkaloid SB-203208.
Reaction Schemes
(3R)-3-methyl-L-phenylalanyl-[peptidyl carrier-protein]
+
(sulfonamide-N)(L-isoleucyl)altemicidin
=
[peptidyl carrier-protein]
+
SB-203208
Synonyms sbzC ,
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sbzC
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(3R)-3-methyl-L-phenylalanyl-[peptidyl carrier-protein] + (sulfonamide-N)(L-isoleucyl)altemicidin = [peptidyl carrier-protein] + SB-203208
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(3R)-3-methyl-L-phenylalanyl-[peptidyl carrier-protein]:(sulfonamide-N)(L-isoleucyl)altemicidin O-(3R)-3-methyl-L-phenylalanyl-transferase
The enzyme, characterized from the bacterium Streptomyces sioyaensis, catalyses the last step in the biosynthesis of the monoterpene alkaloid SB-203208.
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(3R)-3-methyl-L-phenylalanyl-[peptidyl carrier-protein] + SB-203207
[peptidyl carrier-protein] + SB-203208
(3R)-3-methyl-L-phenylalanyl-[peptidyl carrier-protein] + SB-203207
[peptidyl carrier-protein] + SB-203208
A0A3T0ZHH3
Substrates: -
?
(3R)-3-methyl-L-phenylalanyl-[peptidyl carrier-protein] + SB-203207
[peptidyl carrier-protein] + SB-203208
A0A3T0ZHH3
Substrates: SB-203207 i.e. (sulfonamide-N)(L-isoleucyl)altemidicin. SB-203208 i.e. (4aR,6S,7R,7aS)-4-(carbamonyl)-7-([[(2S,3S)-2-amino-3-methylpentanoyl]-aminosulphonyl]acetamido)-6-[[(2S,3S)-2-amino-3-phenylbutanoyl]oxy]-2-methyl-1,4a,5,6,7,7a-hexahydro-2H-cyclopents[c]pyrindine-7-carboxylate
?
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(3R)-3-methyl-L-phenylalanyl-[peptidyl carrier-protein] + SB-203207
[peptidyl carrier-protein] + SB-203208
A0A3T0ZHH3
Substrates: -
?
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A0A3T0ZHH3
GenBank
brenda
Highest Expressing Human Cell Lines
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metabolism
A0A3T0ZHH3
the enzyme catalyses the last step in the biosynthesis of the monoterpene alkaloid SB-203208
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expressed in Escherichia coli Rosetta2 (DE3) cells
A0A3T0ZHH3
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Hu, Z.; Awakawa, T.; Ma, Z.; Abe, I.
Aminoacyl sulfonamide assembly in SB-203208 biosynthesis
Nat. Commun.
10
184
2019
Streptomyces sp. NCIMB40513 (A0A3T0ZHH3)
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