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2 S-adenosyl-L-methionine + squalene = 2 S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
overall reaction
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S-adenosyl-L-methionine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene = S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
1b
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S-adenosyl-L-methionine + squalene = S-adenosyl-L-homocysteine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene
1a
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2 S-adenosyl-L-methionine + squalene
2 S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
S-adenosyl-L-methionine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene
S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
S-adenosyl-L-methionine + squalene
S-adenosyl-L-homocysteine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene
additional information
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Substrates: mono- and dimethylated products with terminal carbon C-3 as the atomic acceptor sites for the methyl additions to squalene, NMR analysis, overview TMT-1 and TMT-2 show only low activity with C30 botryococcene
Products: -
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2 S-adenosyl-L-methionine + squalene
2 S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
-
Substrates: overall reaction
Products: -
ir
2 S-adenosyl-L-methionine + squalene
2 S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
-
Substrates: overall reaction
Products: -
ir
S-adenosyl-L-methionine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene
S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
-
Substrates: -
Products: -
?
S-adenosyl-L-methionine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene
S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
-
Substrates: -
Products: -
?
S-adenosyl-L-methionine + squalene
S-adenosyl-L-homocysteine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene
-
Substrates: -
Products: -
?
S-adenosyl-L-methionine + squalene
S-adenosyl-L-homocysteine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene
-
Substrates: -
Products: -
?
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2 S-adenosyl-L-methionine + squalene
2 S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
S-adenosyl-L-methionine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene
S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
S-adenosyl-L-methionine + squalene
S-adenosyl-L-homocysteine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene
2 S-adenosyl-L-methionine + squalene
2 S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
-
Substrates: overall reaction
Products: -
ir
2 S-adenosyl-L-methionine + squalene
2 S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
-
Substrates: overall reaction
Products: -
ir
S-adenosyl-L-methionine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene
S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
-
Substrates: -
Products: -
?
S-adenosyl-L-methionine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene
S-adenosyl-L-homocysteine + 3,22-dimethyl-1,2,23,24-tetradehydro-2,3,22,23-tetrahydrosqualene
-
Substrates: -
Products: -
?
S-adenosyl-L-methionine + squalene
S-adenosyl-L-homocysteine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene
-
Substrates: -
Products: -
?
S-adenosyl-L-methionine + squalene
S-adenosyl-L-homocysteine + 3-methyl-1,2-didehydro-2,3-dihydrosqualene
-
Substrates: -
Products: -
?
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Hallux Valgus
Bioabsorbable vs. titanium screws for first tarsometatarsal joint arthrodesis: An in-vitro study.
Hallux Valgus
Modified Lapidus arthrodesis with plantar plate and compression screw for treatment of hallux valgus with hypermobility of the first ray: A preliminary report.
Neoplasms
Isolation of mouse mammary tumor cells showing spontaneous regression.
Neoplasms
Two new C3H mouse ascites tumor cell lines capable of proliferation in vivo and in suspension culture: morphological, karyological, kinetic and immunological properties.
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Niehaus, T.D.; Kinison, S.; Okada, S.; Yeo, Y.S.; Bell, S.A.; Cui, P.; Devarenne, T.P.; Chappell, J.
Functional identification of triterpene methyltransferases from Botryococcus braunii race B
J. Biol. Chem.
287
8163-8173
2012
Botryococcus braunii, Botryococcus braunii race B
brenda
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