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Information on EC 1.17.9.1 - 4-methylphenol dehydrogenase (hydroxylating)

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EC Tree
     1 Oxidoreductases
         1.17 Acting on CH or CH2 groups
            
                1.17.9.1 4-methylphenol dehydrogenase (hydroxylating)
IUBMB Comments
A flavocytochrome c (FAD). Phenazine methosulfate can act as acceptor. A quinone methide is probably formed as intermediate. The first hydroxylation forms 4-hydroxybenzyl alcohol; a second hydroxylation converts this into 4-hydroxybenzaldehyde.
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Word Map
The expected taxonomic range for this enzyme is: Bacteria, Eukaryota
Reaction Schemes
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Synonyms
p-cresol methylhydroxylase, p-cresol methylhydroxylases, p-cresol methylhydroxylase a, para-cresol methylhydroxylase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
4-hydroxybenzyl alcohol + 2 oxidized azurin = 4-hydroxybenzaldehyde + 2 reduced azurin + 2 H+
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(1b)
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4-methylphenol + 2 oxidized azurin + H2O = 4-hydroxybenzyl alcohol + 2 reduced azurin + 2 H+
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(1a)
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4-methylphenol + 4 oxidized azurin + H2O = 4-hydroxybenzaldehyde + 4 reduced azurin + 4 H+
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