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Information on EC 1.14.15.32 - pentalenene oxygenase

for references in articles please use BRENDA:EC1.14.15.32
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IUBMB Comments
A heme-thiolate protein (P-450). The enzyme is involved in the biosynthesis of pentalenolactone and related antibiotics.
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The expected taxonomic range for this enzyme is: Streptomyces avermitilis
Reaction Schemes
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+
4
reduced ferredoxin [iron-sulfur] cluster
+
4
+
2
=
+
4
oxidized ferredoxin [iron-sulfur] cluster
+
3
Synonyms
CYP183A1, PtlI, SAV2999, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
pentalen-13-ol + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+ + O2 = pentalen-13-al + 2 oxidized ferredoxin [iron-sulfur] cluster + 2 H2O
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(1b)
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-
-
pentalenene + 2 reduced ferredoxin [iron-sulfur] cluster + 2 H+ + O2 = pentalen-13-ol + 2 oxidized ferredoxin [iron-sulfur] cluster + H2O
show the reaction diagram
(1a)
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-
-
pentalenene + 4 reduced ferredoxin [iron-sulfur] cluster + 4 H+ + 2 O2 = pentalen-13-al + 4 oxidized ferredoxin [iron-sulfur] cluster + 3 H2O
show the reaction diagram
overall reaction
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