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Information on EC 1.14.14.41 - (E)-2-methylbutanal oxime monooxygenase

for references in articles please use BRENDA:EC1.14.14.41
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IUBMB Comments
This cytochrome P-450 (heme thiolate) enzyme is involved in the biosynthesis of the cyanogenic glucosides lotaustralin and linamarin. It catalyses three different activities - isomerization of its substrate, the (E) isomer, to the (Z) isomer, dehydration, and C-hydroxylation.
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The expected taxonomic range for this enzyme is: Manihot esculenta
Synonyms
cyp71e7, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
(E)-2-methylbutanal oxime + [reduced NADPH-hemoprotein reductase] + O2 = 2-hydroxy-2-methylbutanenitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O
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(1) overall reaction
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(E)-2-methylbutanal oxime = (Z)-2-methylbutanal oxime
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(1a)
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(E)-2-methylpropanal oxime + [reduced NADPH-hemoprotein reductase] + O2 = 2-hydroxy-2-methylpropanenitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O
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(2) overall reaction
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(E)-2-methylpropanal oxime = (Z)-2-methylpropanal oxime
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(2a)
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(Z)-2-methylbutanal oxime = 2-methylbutanenitrile + H2O
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(1b)
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(Z)-2-methylpropanal oxime = 2-methylpropanenitrile + H2O
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(2b)
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2-methylbutanenitrile + [reduced NADPH-hemoprotein reductase] + O2 = 2-hydroxy-2-methylbutanenitrile + [oxidized NADPH-hemoprotein reductase] + H2O
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(1c)
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2-methylpropanenitrile + [reduced NADPH-hemoprotein reductase] + O2 = 2-hydroxy-2-methylpropanenitrile + [oxidized NADPH-hemoprotein reductase] + H2O
show the reaction diagram
catalytic reaction mechanism, detailed overview
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