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Information on EC 1.14.13.247 - stachydrine N-demethylase

for references in articles please use BRENDA:EC1.14.13.247
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IUBMB Comments
The enzyme, characterized from the bacterium Sinorhizobium meliloti 1021, consists of three different types of subunits. The catalytic unit contains a Rieske [2Fe-2S] iron-sulfur cluster, and catalyses the monooxygenation of a methyl group. The resulting N-methoxyl group is unstable and decomposes spontaneously to form formaldehyde. The other subunits are involved in the transfer of electrons from NAD(P)H to the catalytic subunit.
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The expected taxonomic range for this enzyme is: Alphaproteobacteria
Synonyms
HpbB1-HpbC1, HpbB2-HpbC2, L-proline betaine N-demethylase, stachydrine demethylase, stc2, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
L-proline betaine + NAD(P)H + H+ + O2 = N-methyl-L-proline + formaldehyde + NAD(P)+ + H2O
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PATHWAY SOURCE
PATHWAYS
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