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Information on EC 1.1.3.47 - 5-(hydroxymethyl)furfural oxidase

for references in articles please use BRENDA:EC1.1.3.47
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EC Tree
IUBMB Comments
The enzyme, characterized from the bacterium Methylovorus sp. strain MP688, is involved in the degradation and detoxification of 5-(hydroxymethyl)furfural. The enzyme acts only on alcohol groups and requires the spontaneous hydration of aldehyde groups for their oxidation . The enzyme has a broad substrate range that overlaps with EC 1.1.3.7, aryl-alcohol oxidase.
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Word Map
The expected taxonomic range for this enzyme is: Bacteria, Eukaryota
Reaction Schemes
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Synonyms
5-hydroxymethylfurfural oxidase, AAO, HFMO, HMF oxidase, HMF/furfural oxidoreductase, HmfH, HMFO, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
5-(dihydroxymethyl)furan-2-carbaldehyde + O2 = 5-formylfuran-2-carboxylate + H2O2
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(1c)
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5-(dihydroxymethyl)furan-2-carboxylate + O2 = furan-2,5-dicarboxylate + H2O2
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(1e)
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5-(hydroxymethyl)furfural + 3 O2 + 2 H2O = furan-2,5-dicarboxylate + 3 H2O2
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overall reaction
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5-(hydroxymethyl)furfural + O2 = furan-2,5-dicarbaldehyde + H2O2
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(1a)
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5-formylfuran-2-carboxylate + H2O = 5-(dihydroxymethyl)furan-2-carboxylate
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(1d), spontaneous
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furan-2,5-dicarbaldehyde + H2O = 5-(dihydroxymethyl)furan-2-carbaldehyde
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(1b), spontaneous
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