1.97.1.2: pyrogallol hydroxytransferase
This is an abbreviated version!
For detailed information about pyrogallol hydroxytransferase, go to the full flat file.
Word Map on EC 1.97.1.2
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1.97.1.2
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pelobacter
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molybdenum
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heterodimer
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epr
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beta-subunits
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p-chloromercuribenzoate
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sulfide
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cosubstrate
-
dithionite
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acid-labile
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acetylene
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desulfovibrio
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trihydroxybenzenes
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tungsten
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molybdopterin
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dehydroxylation
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1,2,4-trihydroxybenzene
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phenol
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dimethylsulfoxide
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hydroxyhydroquinone
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guanine
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hydratase
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alpha-subunit
- 1.97.1.2
-
pelobacter
- molybdenum
- heterodimer
- epr
- beta-subunits
- p-chloromercuribenzoate
- sulfide
-
cosubstrate
- dithionite
-
acid-labile
- acetylene
- desulfovibrio
-
trihydroxybenzenes
- tungsten
- molybdopterin
-
dehydroxylation
- 1,2,4-trihydroxybenzene
- phenol
- dimethylsulfoxide
- hydroxyhydroquinone
- guanine
-
hydratase
- alpha-subunit
Reaction
Synonyms
1,2,3,5-tetrahydroxybenzene-pyrogallol hydroxyltransferase, 1,2,3,5-tetrahydroxybenzene:pyrogallol transhydroxylase, hydroxyltransferase, 1,2,3,5-tetrahydroxybenzene, pyrogallol hydroxyltransferase, pyrogallol phloroglucinol transhydroxylase, pyrogallol:phloroglucinol hydroxyltransferase, transhydroxylase
ECTree
1.97.1.2 pyrogallol hydroxytransferaseAdvanced search results
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results (Substrates Products
Substrates Products on EC 1.97.1.2 - pyrogallol hydroxytransferase
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SUBSTRATE 
PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate)
(Substrate)
LITERATURE
(Substrate)
(Substrate)
COMMENTARY
(Product)
(Product)
LITERATURE
(Product)
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
r=reversible
ir=irreversible
?=not specified
1,2,3,5-tetrahydroxybenzene + 1,2,3,5-tetrahydroxybenzene
phloroglucinol + pentahydroxybenzene
1,2,3,5-tetrahydroxybenzene + 1,2,3-trihydroxybenzene
1,3,5-trihydroxybenzene + 1,2,3,5-tetrahydroxybenzene
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2,4,6,3,4,5-hexahydroxydiphenyl ether and 3,4,5,3,4,5-hexahydroxydiphenyl ether can substitute for the cocatalyst 1,2,3,5-tetrahydroxybenzene in vitro. This indicates that the diphenyl ethers can intrude into the active site and initiate the catalytic cycle
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-
?
1,2,3,5-tetrahydroxybenzene + hydroxyhydroquinone
phloroglucinol + 1,2,4,5-tetrahydroxybenzene
1,2,4,5-tetrahydroxybenzene + pyrogallol
hydroxyhydroquinone + 1,2,3,5-tetrahydroxybenzene
-
-
-
?
1,2,3,5-tetrahydroxybenzene + 1,2,3,5-tetrahydroxybenzene
phloroglucinol + pentahydroxybenzene
-
-
tentatively identified
?
1,2,3,5-tetrahydroxybenzene + 1,2,3,5-tetrahydroxybenzene
phloroglucinol + pentahydroxybenzene
-
-
tentatively identified
?
1,2,3,5-tetrahydroxybenzene + 1,2,3,5-tetrahydroxybenzene
phloroglucinol + pentahydroxybenzene
-
-
-
?
1,2,3,5-tetrahydroxybenzene + hydroxyhydroquinone
phloroglucinol + 1,2,4,5-tetrahydroxybenzene
-
-
-
?
1,2,3,5-tetrahydroxybenzene + hydroxyhydroquinone
phloroglucinol + 1,2,4,5-tetrahydroxybenzene
-
-
tentatively identified
?
1,2,3,5-tetrahydroxybenzene + hydroxyhydroquinone
phloroglucinol + 1,2,4,5-tetrahydroxybenzene
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-
-
?
1,2,3,5-tetrahydroxybenzene + pyrogallol
?
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key step in the anaerobic degradation of gallic acid and releated polyphenolic compounds
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-
?
1,2,3,5-tetrahydroxybenzene + pyrogallol
?
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i.e. 1,2,3-trihydroxybenzene, reaction in fermentative degradation of trihydroxy-derivatives, pathway
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-
?
1,2,3,5-tetrahydroxybenzene + pyrogallol
?
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i.e. 1,2,3-trihydroxybenzene, reaction in fermentative degradation of trihydroxy-derivatives, pathway
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-
?
1,2,3,5-tetrahydroxybenzene + pyrogallol
?
-
key step in the anaerobic degradation of gallic acid and releated polyphenolic compounds
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-
?
1,2,3,5-tetrahydroxybenzene + pyrogallol
phloroglucinol + 1,2,3,5-tetrahydroxybenzene
-
pyrogallol i.e. 1,2,3-tri-hydroxybenzene
phloroglucinol i.e. 1,3,5-tri-hydroxybenzene
?
1,2,3,5-tetrahydroxybenzene + pyrogallol
phloroglucinol + 1,2,3,5-tetrahydroxybenzene
-
pyrogallol i.e. 1,2,3-tri-hydroxybenzene
phloroglucinol i.e. 1,3,5-tri-hydroxybenzene
?
1,2,3,5-tetrahydroxybenzene + pyrogallol
phloroglucinol + 1,2,3,5-tetrahydroxybenzene
-
pyrogallol i.e. 1,2,3-tri-hydroxybenzene
phloroglucinol i.e. 1,3,5-tri-hydroxybenzene
?
1,2,3,5-tetrahydroxybenzene + pyrogallol
phloroglucinol + 1,2,3,5-tetrahydroxybenzene
-
pyrogallol i.e. 1,2,3-tri-hydroxybenzene
phloroglucinol i.e. 1,3,5-tri-hydroxybenzene
?
1,2,3,5-tetrahydroxybenzene + pyrogallol
phloroglucinol + 1,2,3,5-tetrahydroxybenzene
-
pyrogallol i.e. 1,2,3-tri-hydroxybenzene
phloroglucinol i.e. 1,3,5-tri-hydroxybenzene
?
1,2,3,5-tetrahydroxybenzene + pyrogallol
phloroglucinol + 1,2,3,5-tetrahydroxybenzene
-
pyrogallol i.e. 1,2,3-tri-hydroxybenzene
phloroglucinol i.e. 1,3,5-tri-hydroxybenzene
r
1,2,3,5-tetrahydroxybenzene + pyrogallol
phloroglucinol + 1,2,3,5-tetrahydroxybenzene
-
pyrogallol i.e. 1,2,3-tri-hydroxybenzene
phloroglucinol i.e. 1,3,5-tri-hydroxybenzene
?
1,2,3,5-tetrahydroxybenzene + pyrogallol
phloroglucinol + 1,2,3,5-tetrahydroxybenzene
-
pyrogallol i.e. 1,2,3-tri-hydroxybenzene
phloroglucinol i.e. 1,3,5-tri-hydroxybenzene
r
1,2,3,5-tetrahydroxybenzene + pyrogallol
phloroglucinol + 1,2,3,5-tetrahydroxybenzene
-
pyrogallol i.e. 1,2,3-tri-hydroxybenzene
phloroglucinol i.e. 1,3,5-tri-hydroxybenzene
?
1,2,3,5-tetrahydroxybenzene + pyrogallol
phloroglucinol + 1,2,3,5-tetrahydroxybenzene
-
pyrogallol i.e. 1,2,3-tri-hydroxybenzene
phloroglucinol i.e. 1,3,5-tri-hydroxybenzene
?
1,2,3,5-tetrahydroxybenzene + resorcinol
phloroglucinol + hydroxyhydroquinone
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-
-
?
1,2,3,5-tetrahydroxybenzene + resorcinol
phloroglucinol + hydroxyhydroquinone
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-
-
-
?
hydroxyhydroquinone + hydroxyhydroquinone
resorcinol + 1,2,4,5-tetrahydroxybenzene
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-
tentatively identified
?
hydroxyhydroquinone + hydroxyhydroquinone
resorcinol + 1,2,4,5-tetrahydroxybenzene
-
-
-
r
hydroxyhydroquinone + pyrogallol
resorcinol + 1,2,3,5-tetrahydroxybenzene
-
hydroxyhydroquinone i.e. 1,2,4-trihydroxybenzene
resorcinol i.e. 1,3-benzenediol
?
hydroxyhydroquinone + pyrogallol
resorcinol + 1,2,3,5-tetrahydroxybenzene
-
hydroxyhydroquinone i.e. 1,2,4-trihydroxybenzene
resorcinol i.e. 1,3-benzenediol
?
hydroxyhydroquinone + pyrogallol
resorcinol + 1,2,3,5-tetrahydroxybenzene
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hydroxyhydroquinone i.e. 1,2,4-trihydroxybenzene
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?
additional information
?
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dimethyl sulfoxide at unphysiological high concentrations can replace 1,2,3,5-tetrahydroxybenzene with 0.04% efficiency, no transhydroxylation takes place with catechol or phenol + 1,2,3,5-tetrahydroxybenzene, pyrogallol + catechol, resorcinol, hydroquinone or phenol
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-
?
additional information
?
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pyrogallol converts to phloroglucinol in the absence of added tetrahydroxybenzene if very little pyrogallol and high amounts of enzyme are present
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-
?
additional information
?
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1,2,3,5-tetrahydroxybenzene, 1,2,4-trihydroxybenzene, effective OH-donors
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-
?
additional information
?
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water is not the source of the added hydroxyl groups
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-
?
additional information
?
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-
water is not the source of the added hydroxyl groups
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-
?
additional information
?
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water is not the source of the added hydroxyl groups
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-
?
additional information
?
-
-
water is not the source of the added hydroxyl groups
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-
?
additional information
?
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intermolecular transhydroxylation
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-
?
additional information
?
-
-
dimethyl sulfoxide at unphysiological high concentrations can replace 1,2,3,5-tetrahydroxybenzene with 0.04% efficiency, no transhydroxylation takes place with catechol or phenol + 1,2,3,5-tetrahydroxybenzene, pyrogallol + catechol, resorcinol, hydroquinone or phenol
-
-
?
additional information
?
-
-
1,2,3,5-tetrahydroxybenzene, 1,2,4-trihydroxybenzene, effective OH-donors
-
-
?
additional information
?
-
-
water is not the source of the added hydroxyl groups
-
-
?
additional information
?
-
-
dimethyl sulfoxide at unphysiological high concentrations can replace 1,2,3,5-tetrahydroxybenzene with 0.04% efficiency, no transhydroxylation takes place with catechol or phenol + 1,2,3,5-tetrahydroxybenzene, pyrogallol + catechol, resorcinol, hydroquinone or phenol
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-
?
additional information
?
-
-
1,2,4,5-tetrahydroxybenzene: OH-donor, pyrogallol, hydroxyhydroquinone and resorcinol: OH-acceptors
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-
?
additional information
?
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-
1,2,3,5-tetrahydroxybenzene, 1,2,4-trihydroxybenzene, effective OH-donors
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-
?
additional information
?
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in the absence of OH-acceptor or at very high donor/acceptor ratio the donors react with themselves and disproportionate to hydroxylated and dehydroxylated products
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-
?
