1.5.3.5: (S)-6-hydroxynicotine oxidase
This is an abbreviated version!
For detailed information about (S)-6-hydroxynicotine oxidase, go to the full flat file.
Word Map on EC 1.5.3.5
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1.5.3.5
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arthrobacter
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6-hydroxy-d-nicotine
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nicotinovorans
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oxidans
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flavin
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fad
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flavoenzyme
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nicotine-degrading
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monoamine
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flavoproteins
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hydride
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6-hydroxypseudooxynicotine
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dehydrogenation
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pseudooxynicotine
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d-specific
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pyrrolidine
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dithionite-reduced
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carbon-carbon
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self-formed
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fad-binding
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s-nicotine
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l-enantiomer
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fitzpatrick
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carbon-nitrogen
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isoalloxazine
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6-hdno
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substrate-reduced
- 1.5.3.5
- arthrobacter
- 6-hydroxy-d-nicotine
- nicotinovorans
- oxidans
- flavin
- fad
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flavoenzyme
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nicotine-degrading
-
monoamine
- flavoproteins
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hydride
- 6-hydroxypseudooxynicotine
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dehydrogenation
- pseudooxynicotine
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d-specific
- pyrrolidine
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dithionite-reduced
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carbon-carbon
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self-formed
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fad-binding
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s-nicotine
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l-enantiomer
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fitzpatrick
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carbon-nitrogen
- isoalloxazine
- 6-hdno
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substrate-reduced
Reaction
Synonyms
6-HLNO, 6-hydroxy-L-nicotine oxidase, 6-hydroxy-L-nicotine:oxygen oxidoreductase, 6HLNO, flavoprotein nicotine oxidoreductase, L-6-hydroxynicotine oxidase, LHNO, MAO, NdpB, NicA2, NOX, VppB
ECTree
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Natural Substrates Products
Natural Substrates Products on EC 1.5.3.5 - (S)-6-hydroxynicotine oxidase
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REACTION DIAGRAM
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one + H2O2
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyridin-3-yl)-4-(methylamino)butan-1-one + H2O2
6-hydroxy-L-nicotine + H2O + O2
6-hydroxy-N-methylmyosmine + NH3 + H2O2
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-
-
-
?
1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one + H2O2
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-
-
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one + H2O2
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-
-
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one + H2O2
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-
-
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one + H2O2
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-
-
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one + H2O2
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-
-
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one + H2O2
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-
-
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one + H2O2
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-
-
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one + H2O2
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-
transitional product is 6-hydroxy-N-methylmyosmine that hydrolyses spontaneously
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one + H2O2
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-
transitional product is 6-hydroxy-N-methylmyosmine that hydrolyses spontaneously
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one + H2O2
-
-
transitional product is 6-hydroxy-N-methylmyosmine that hydrolyses spontaneously
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyrid-3-yl)-4-(methylamino)-butan-1-one + H2O2
-
-
transitional product is 6-hydroxy-N-methylmyosmine that hydrolyses spontaneously
?
1-(6-hydroxypyridin-3-yl)-4-(methylamino)butan-1-one + H2O2
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-
-
-
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyridin-3-yl)-4-(methylamino)butan-1-one + H2O2
-
-
-
-
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyridin-3-yl)-4-(methylamino)butan-1-one + H2O2
the enzyme is involved in degradation of nicotine
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-
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyridin-3-yl)-4-(methylamino)butan-1-one + H2O2
absolute stereospecificity on the L-form
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-
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyridin-3-yl)-4-(methylamino)butan-1-one + H2O2
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the enzyme catalyzes the oxidation of (S)-6-hydroxynicotine to 6-hydroxypseudooxynicotine during microbial catabolism of nicotine
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-
?
(S)-6-hydroxynicotine + H2O + O2
1-(6-hydroxypyridin-3-yl)-4-(methylamino)butan-1-one + H2O2
the enzyme is essential for nicotine or (S)-6-hydroxynicotine degradation
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-
?
?
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transformation of 6-hydroxy-L-nicotine to 6-hydroxy-N-methylmyosmine, 6-hydroxypseudooxynicotine formation, overview
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-
?
additional information
?
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transformation of 6-hydroxy-L-nicotine to 6-hydroxy-N-methylmyosmine, 6-hydroxypseudooxynicotine formation, overview
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?
additional information
?
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enzyme production is induced by growing cells in D,L-nicotine as only source of carbon and nitrogen
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?
additional information
?
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enzyme production is induced by growing cells in D,L-nicotine as only source of carbon and nitrogen
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?
additional information
?
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enzyme production is induced by growing cells in D,L-nicotine as only source of carbon and nitrogen
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-
?
additional information
?
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it is synthesized only during the logarithmic and stationary phases of growth
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?
additional information
?
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no activity with 6-hydroxy-D-nicotine
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-
?