1.3.1.81: (+)-pulegone reductase
This is an abbreviated version!
For detailed information about (+)-pulegone reductase, go to the full flat file.
Word Map on EC 1.3.1.81
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1.3.1.81
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peppermint
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+-pulegone
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mentha
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monoterpene
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piperita
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+-menthofuran
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monoterpenoids
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glandular
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trichomes
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geranyl
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peltate
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terpenoids
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p-menthane
- 1.3.1.81
- peppermint
-
+-pulegone
- mentha
-
monoterpene
- piperita
-
+-menthofuran
-
monoterpenoids
-
glandular
- trichomes
-
geranyl
-
peltate
-
terpenoids
-
p-menthane
Reaction
Synonyms
(+)-pulegone reductase, More, pulegone reductase
ECTree
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Substrates Products
Substrates Products on EC 1.3.1.81 - (+)-pulegone reductase
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REACTION DIAGRAM
(-)-menthone + (+)-isomenthone + 2 NADP+
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2 (+)-pulegone + 2 NADPH + 2 H+
(-)-menthone + (+)-isomenthone + 2 NADP+
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pathways of monoterpene biosynthesis, overview
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2 (+)-pulegone + 2 NADPH + 2 H+
(-)-menthone + (+)-isomenthone + 2 NADP+
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2 (+)-pulegone + 2 NADPH + 2 H+
(-)-menthone + (+)-isomenthone + 2 NADP+
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ratio of 90% (-)-menthone and 10% (+)-isomenthone
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r
2 (+)-pulegone + 2 NADPH + 2 H+
(-)-menthone + (+)-isomenthone + 2 NADP+
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branchpoint enzyme in essential oil biosynthesis
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2 (+)-pulegone + 2 NADPH + 2 H+
(-)-menthone + (+)-isomenthone + 2 NADP+
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pathways of monoterpene biosynthesis, overview
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2 (+)-pulegone + 2 NADPH + 2 H+
(-)-menthone + (+)-isomenthone + 2 NADP+
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regulation of pulegone metabolism involves menthofuran, the flux of (+)-pulegone through pulegone reductase correlates negatively with the essential oil content of menthofuran, such that menthofuran, and pulegone increase, or decrease, in concert, overview
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2 (+)-pulegone + 2 NADPH + 2 H+
(-)-menthone + (+)-isomenthone + 2 NADP+
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the enzyme is required for catalyzation of the reduction of the DELTA4,8 double bond to produce menthone on route to menthol, monoterpene biosynthetic pathways in peppermint, overview
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2 (+)-pulegone + 2 NADPH + 2 H+
(-)-menthone + (+)-isomenthone + 2 NADP+
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the NADPH-dependent reductase reduces the conjugated double bond to yield both (-)-menthone and (+)-isomenthone
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2 (+)-pulegone + 2 NADPH + 2 H+
(-)-menthone + (+)-isomenthone + 2 NADP+
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the reductase catalyzes the reduction of the 4(8)-double bond of (+)-pulegone to produce both (-)-menthone and (+)-isomenthone in a 70:30 ratio
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2 (+)-pulegone + 2 NADPH + 2 H+
(-)-menthone + (+)-isomenthone + 2 NADP+
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the reductase catalyzes the reduction of the 4(8)-double bond of (+)-pulegone to produce both (-)-menthone and (+)-isomenthone in a 70:30 ratio, product analysis by GC-MS, stereospecific reductase
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kinetic modeling and simulations of the developmental patterns of monoterpenoid essential oil accumulation in peppermint, overview
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additional information
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pathways for monoterpene biosynthesis in peppermint, overview
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